Publication Year | Author | Title | Publication Title | DOI | Url | Pages | Issue | Volume |
---|---|---|---|---|---|---|---|---|
2016 | Syu, Yu-Kai; Tingare, Yogesh; Yeh, Chen-Yu; Yang, Jih-Sheng; Wu, Jih-Jen | Panchromatic engineering for efficient zinc oxide flexible dye-sensitized solar cells using porphyrin and indoline dyes | RSC Advances | 10.1039/C6RA09262D | https://pubs.rsc.org/en/content/articlelanding/2016/ra/c6ra09262d | 59273-59279 | 64 | 6 |
2016 | Syu, Yu-Kai; Tingare, Yogesh; Lin, Shou-Yen; Yeh, Chen-Yu; Wu, Jih-Jen | Porphyrin Dye-Sensitized Zinc Oxide Aggregated Anodes for Use in Solar Cells | Molecules | 10.3390/molecules21081025 | https://www.mdpi.com/1420-3049/21/8/1025 | 1025 | 8 | 21 |
2015 | Higashino, Tomohiro; Fujimori, Yamato; Sugiura, Kenichi; Tsuji, Yukihiro; Ito, Seigo; Imahori, Hiroshi | Tropolone as a High-Performance Robust Anchoring Group for Dye-Sensitized Solar Cells | Angewandte Chemie International Edition | 10.1002/anie.201502951 | https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201502951 | 9052-9056 | 31 | 54 |
2016 | Yen, Chih-Ping; Yu, Pin-Feng; Wang, Jyhpyng; Lin, Jiunn-Yuan; Chen, Yen-Mu; Chen, Szu-yuan | Deposition of organic dyes for dye-sensitized solar cell by using matrix-assisted pulsed laser evaporation | AIP Advances | 10.1063/1.4961380 | https://doi.org/10.1063/1.4961380 | 85011 | 8 | 6 |
2017 | Lee, Geon Hyeong; and Kim, Young Sik | Theoretical study of novel porphyrin-based dye for efficient dye-sensitized solar cell | Molecular Crystals and Liquid Crystals | 10.1080/15421406.2016.1277636 | https://doi.org/10.1080/15421406.2016.1277636 | 168-174 | 1 | 645 |
2023 | Demirci, Yi?it Can; ?akar, Soner; Sevim, Altu? Mert; G?l, Ahmet; ?zacar, Mahmut | DSSCs based on unsymmetrical A3B type Zn(II) and TiO(IV) naphthalenephthalocyanine/porphyrin cocktail dyes: A potential alternative for ruthenium based sensitizers | Journal of Photochemistry and Photobiology A: Chemistry | 10.1016/j.jphotochem.2023.114642 | https://www.sciencedirect.com/science/article/pii/S1010603023001077 | 114642 | 440 | |
2025 | S?erkan, ?eyma Nur; Arslan, Nuray; G?k?e?ren, Argun Talat; ?akar, Soner; Sevim, Altu? Mert; G?l, Ahmet; ?zacar, Mahmut | A3B type Zn(II) phthalocyanines and porphyrin cocktail dye sensitizers for highly efficient DSSCs | Journal of Photochemistry and Photobiology A: Chemistry | 10.1016/j.jphotochem.2025.116333 | https://www.sciencedirect.com/science/article/pii/S1010603025000735 | 116333 | 464 | |
2023 | Arslan, Nuray; Yildirir, ?eyma Nur; Sevim, Altu? Mert; ?akar, Soner; ?zacar, Mahmut; G?l, Ahmet | Sulfur-bridged oxotitanium phthalocyanine- and porphyrin-based cocktail dyes as sensitizers for improved dye sensitized solar cell efficiency | Dyes and Pigments | 10.1016/j.dyepig.2023.111623 | https://www.sciencedirect.com/science/article/pii/S0143720823005491 | 111623 | 220 | |
2018 | Zhu, Han-Cheng; Zhang, Ji; Wang, Ying-Lin | Adsorption orientation effects of porphyrin dyes on the performance of DSSC: Comparison of benzoic acid and tropolone anchoring groups binding onto the TiO2 anatase (101) surface | Applied Surface Science | 10.1016/j.apsusc.2017.10.087 | https://www.sciencedirect.com/science/article/pii/S0169433217330301 | 1137-1147 | 433 | |
2019 | Yang, Li-Na; Lin, Li-Guang; Meng, A-Lan; Li, Zhen-Jiang | Theoretical insights into co-sensitization mechanism in Zn-porphyrin and Y123 co-sensitized solar cells | Journal of Photochemistry and Photobiology A: Chemistry | 10.1016/j.jphotochem.2018.10.014 | https://www.sciencedirect.com/science/article/pii/S1010603018311006 | 25-33 | 369 | |
2019 | Lee, Byunghong; Ezhumalai, Yamuna; Lee, Woongkyu; Chen, Ming-Chou; Yeh, Chen-Yu; Marks, Tobin J.; Chang, Robert P. H. | Cs2SnI6-Encapsulated Multidye-Sensitized All-Solid-State Solar Cells | ACS Applied Materials & Interfaces | 10.1021/acsami.8b19778 | https://doi.org/10.1021/acsami.8b19778 | 21424-21434 | 24 | 11 |
2016 | Molla, Md Zaman; Kawano, Minobu; Baranwal, Ajay K.; Pandey, Shyam S.; Ogomi, Yuhei; Ma, Tingli; Hayase, Shuzi | Enhancing the performance of transparent conductive oxide-less back contact dye-sensitized solar cells by facile diffusion of cobalt species through TiO2 nanopores | RSC Advances | 10.1039/C6RA04894C | https://pubs.rsc.org/en/content/articlelanding/2016/ra/c6ra04894c | 33353-33360 | 40 | 6 |
2022 | Zhang, Hai; Zhou, Jing; Zang, Xu-Feng; Hong, Yan-Ping; Chen, Zhen-E | An efficient strategy for designing high-performance DSSCs: Using the terminal auxiliary acceptor to improve electronic transitions | Dyes and Pigments | 10.1016/j.dyepig.2022.110642 | https://www.sciencedirect.com/science/article/pii/S0143720822005642 | 110642 | 206 | |
2018 | Hajizadeh, Fatemeh; Reisi-Vanani, Adel; Azar, Yavar T. | Theoretical design of Zn-dithiaporphyrins as sensitizer for dye-sensitized solar cells | Current Applied Physics | 10.1016/j.cap.2018.06.011 | https://www.sciencedirect.com/science/article/pii/S1567173918301792 | 1122-1133 | 10 | 18 |
2017 | Mendizabal, Fernando; Mera-Adasme, Ra?l; Xu, Wen-Hua; Sundholm, Dage | Electronic and optical properties of metalloporphyrins of zinc on TiO2 cluster in dye-sensitized solar-cells (DSSC). A quantum chemistry study | RSC Advances | 10.1039/C7RA08648B | https://pubs.rsc.org/en/content/articlelanding/2017/ra/c7ra08648b | 42677-42684 | 68 | 7 |
2021 | Santos, F?tima; Hora, Carolina; Ivanou, Dzmitry; Mendes, Ad?lio M. | Efficient Liquid-Junction Monolithic Cobalt-Mediated Dye-Sensitized Solar Cells for Solar and Artificial Light Conversion | ACS Applied Energy Materials | 10.1021/acsaem.1c00616 | https://doi.org/10.1021/acsaem.1c00616 | 5050-5058 | 5 | 4 |
2017 | Higashino, Tomohiro; Nimura, Shimpei; Sugiura, Kenichi; Kurumisawa, Yuma; Tsuji, Yukihiro; Imahori, Hiroshi | Photovoltaic Properties and Long-Term Durability of Porphyrin-Sensitized Solar Cells with Silicon-Based Anchoring Groups | ACS Omega | 10.1021/acsomega.7b01290 | https://doi.org/10.1021/acsomega.7b01290 | 6958-6967 | 10 | 2 |
2014 | Molla, Md. Zaman; Mizukoshi, Norihiro; Furukawa, Hiroaki; Ogomi, Yuhei; Pandey, Shyam S.; Ma, Tingli; Hayase, Shuzi | Transparent conductive oxide-less back contact dye-sensitized solar cells using cobalt electrolyte | Progress in Photovoltaics: Research and Applications | 10.1002/pip.2526 | https://onlinelibrary.wiley.com/doi/abs/10.1002/pip.2526 | 1100-1109 | 9 | 23 |
2025 | Kodji, Nouake; , Souop Tala Foadin ,Crevain; , Mohammadou ,Sali; , Tchangnwa Nya ,Fridolin; and Ejuh, Geh Wilson | Implementation of bridged copolymerisation to optimise the optical properties of porphyrin: applications in dye-sensitized solar cells | Molecular Physics | 10.1080/00268976.2024.2345727 | https://doi.org/10.1080/00268976.2024.2345727 | e2345727 | 1 | 123 |
2023 | Liao, Jian-Ming; Chin, Yu-Kai; Wu, Yu-Ting; Chou, Hsien-Hsin | Effect of regio-specific arylamine substitution on novel ƒÎ-extended zinc salophen complexes: density functional and time-dependent density functional study on DSSC applications | RSC Advances | 10.1039/D2RA07571G | https://pubs.rsc.org/en/content/articlelanding/2023/ra/d2ra07571g | 2501-2513 | 4 | 13 |
2016 | Peng, Jia-De; Tseng, Chuan-Ming; Vittal, R.; Ho, Kuo-Chuan | Mesoporous anatase-TiO2 spheres consisting of nanosheets of exposed (001)-facets for [Co(byp)3]2+/3+ based dye-sensitized solar cells | Nano Energy | 10.1016/j.nanoen.2016.01.025 | https://www.sciencedirect.com/science/article/pii/S2211285516000458 | 136-148 | 22 |
以下に、アップロードいただいたデータに基づき、物質・方法・新発見を中心にまとめ、雑誌名・年号も明記した要約(DSSC関連)を日本語と英語の両方でご提供します。
🧪 色素増感太陽電池(DSSC)研究の物質・方法・新発見の整理
🔬物質
- 共通材料:ポルフィリン系色素(YD2-o-C8など)、Zn(II)/Ti(IV)ナフタレンフタロシアニン、A3B型ファロシアニン、サロフェン錯体、トロポロン、シラン系アンカー。
- 電解質・添加剤:Co(bpy)₃²⁺/³⁺、CDCA(コアドソーバント)、TiO₂メソポーラス構造(アナターゼ型)。
- 補助光吸収層:ZnPc, TiOPc とのカクテル構成や、Zn-salophenなどを用いた補助吸収色素。
- 新規設計分子:架橋共重合体ポルフィリン、D-π-A構造の電子供与基/アクセプター修飾系。
⚙方法
- 共感光色素法(co-sensitization):YD2-o-C8と他色素(例:ZnPc, TiOPc, ZS12)を特定比率で組合せ、広帯域吸収性とIPCE向上を達成(例:2025年, J. Photochem. Photobiol. A)。
- アンカリング基の工夫:カルボン酸→シラン、トロポロンへの置換により長期耐久性やTiO₂表面との結合強度向上(2017年 ACS Omega, 2015年 Angew. Chem.)。
- 量子化学解析:DFTおよびTD-DFTを用いた軌道解析や、電子注入・再生成エネルギーの定量評価(複数論文、例:2017年 Mol. Cryst. Liq. Cryst.)。
- デバイス構成最適化:メソポーラスTiO₂の(001)面露出制御(2016年 Nano Energy)、TCOレス構造(2016年 RSC Adv.)など。
🌟新発見
- 効率向上:YD2 + ZnPc系(3:1)で最大変換効率10.87%、TiOPc系で10.72%を達成(2025年, J. Photochem. Photobiol. A)。
- 安定性と結合性:トロポロンやシランアンカーにより、YD2-o-C8よりも優れた長期安定性が確認(2015–2017)。
- 吸収拡張・可視~近赤外対応:A3B型非対称ファロシアニンとYD2の組合せで、N719を上回る吸収帯域と性能(2025年 J. Photochem. Photobiol. A)。
- ナノ構造の活用:アナターゼTiO₂球状構造と表面反射で光捕集性向上(2016年 Nano Energy)、コバルト系電解質との親和性向上。
🇬🇧 Summary in English (Materials / Methods / Key Findings)
🔬Materials
- Common dyes: Porphyrins (YD2-o-C8), Zn/Ti-phthalocyanines, A3B-type dyes, Zn-salophen complexes, tropolone/silanized anchors.
- Electrolytes & additives: Cobalt-based redox shuttles (Co(bpy)₃²⁺/³⁺), CDCA, anatase-type mesoporous TiO₂.
- Novel molecules: Bridged porphyrin copolymers, D–π–A type sensitizers, phthalocyanine–porphyrin dye cocktails.
⚙Methods
- Co-sensitization: Strategic dye pairing (e.g., YD2 + ZnPc or TiOPc in 3:1 ratio) achieved high efficiency and broad spectral response (2025, J. Photochem. Photobiol. A).
- Anchoring optimization: Replacing conventional carboxylic acids with tropolone or silane improved dye stability and TiO₂ binding (2015–2017).
- Theoretical approach: DFT/TD-DFT studies to optimize energy levels, transition characteristics, and charge dynamics (multiple papers).
- Device innovations: Enhanced light harvesting via (001)-facet TiO₂ microspheres, and TCO-less back-contact DSSCs (2016, Nano Energy; RSC Advances).
🌟Key Findings
- High efficiencies: Achieved PCE up to 10.87% with YD2:ZnPc (3:1), and 10.72% with YD2:TiOPc combinations (2025).
- Enhanced stability: Tropolone and silane anchor groups provided superior long-term durability over YD2-o-C8.
- Broader absorption: A3B ZnPc derivatives and porphyrin cocktails exceeded N719’s performance, extending into the NIR range.
- Nanostructure benefits: Mesoporous TiO₂ with high (001) facet exposure enhanced dye coverage and reflectivity, boosting Jsc and Voc.
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