DSSC YD2 Paper List

Publication YearAuthorTitlePublication TitleDOIUrlPagesIssueVolume
2016Syu, Yu-Kai; Tingare, Yogesh; Yeh, Chen-Yu; Yang, Jih-Sheng; Wu, Jih-JenPanchromatic engineering for efficient zinc oxide flexible dye-sensitized solar cells using porphyrin and indoline dyesRSC Advances10.1039/C6RA09262Dhttps://pubs.rsc.org/en/content/articlelanding/2016/ra/c6ra09262d59273-59279646
2016Syu, Yu-Kai; Tingare, Yogesh; Lin, Shou-Yen; Yeh, Chen-Yu; Wu, Jih-JenPorphyrin Dye-Sensitized Zinc Oxide Aggregated Anodes for Use in Solar CellsMolecules10.3390/molecules21081025https://www.mdpi.com/1420-3049/21/8/10251025821
2015Higashino, Tomohiro; Fujimori, Yamato; Sugiura, Kenichi; Tsuji, Yukihiro; Ito, Seigo; Imahori, HiroshiTropolone as a High-Performance Robust Anchoring Group for Dye-Sensitized Solar CellsAngewandte Chemie International Edition10.1002/anie.201502951https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.2015029519052-90563154
2016Yen, Chih-Ping; Yu, Pin-Feng; Wang, Jyhpyng; Lin, Jiunn-Yuan; Chen, Yen-Mu; Chen, Szu-yuanDeposition of organic dyes for dye-sensitized solar cell by using matrix-assisted pulsed laser evaporationAIP Advances10.1063/1.4961380https://doi.org/10.1063/1.49613808501186
2017Lee, Geon Hyeong; and Kim, Young SikTheoretical study of novel porphyrin-based dye for efficient dye-sensitized solar cellMolecular Crystals and Liquid Crystals10.1080/15421406.2016.1277636https://doi.org/10.1080/15421406.2016.1277636168-1741645
2023Demirci, Yi?it Can; ?akar, Soner; Sevim, Altu? Mert; G?l, Ahmet; ?zacar, MahmutDSSCs based on unsymmetrical A3B type Zn(II) and TiO(IV) naphthalenephthalocyanine/porphyrin cocktail dyes: A potential alternative for ruthenium based sensitizersJournal of Photochemistry and Photobiology A: Chemistry10.1016/j.jphotochem.2023.114642https://www.sciencedirect.com/science/article/pii/S1010603023001077114642440
2025S?erkan, ?eyma Nur; Arslan, Nuray; G?k?e?ren, Argun Talat; ?akar, Soner; Sevim, Altu? Mert; G?l, Ahmet; ?zacar, MahmutA3B type Zn(II) phthalocyanines and porphyrin cocktail dye sensitizers for highly efficient DSSCsJournal of Photochemistry and Photobiology A: Chemistry10.1016/j.jphotochem.2025.116333https://www.sciencedirect.com/science/article/pii/S1010603025000735116333464
2023Arslan, Nuray; Yildirir, ?eyma Nur; Sevim, Altu? Mert; ?akar, Soner; ?zacar, Mahmut; G?l, AhmetSulfur-bridged oxotitanium phthalocyanine- and porphyrin-based cocktail dyes as sensitizers for improved dye sensitized solar cell efficiencyDyes and Pigments10.1016/j.dyepig.2023.111623https://www.sciencedirect.com/science/article/pii/S0143720823005491111623220
2018Zhu, Han-Cheng; Zhang, Ji; Wang, Ying-LinAdsorption orientation effects of porphyrin dyes on the performance of DSSC: Comparison of benzoic acid and tropolone anchoring groups binding onto the TiO2 anatase (101) surfaceApplied Surface Science10.1016/j.apsusc.2017.10.087https://www.sciencedirect.com/science/article/pii/S01694332173303011137-1147433
2019Yang, Li-Na; Lin, Li-Guang; Meng, A-Lan; Li, Zhen-JiangTheoretical insights into co-sensitization mechanism in Zn-porphyrin and Y123 co-sensitized solar cellsJournal of Photochemistry and Photobiology A: Chemistry10.1016/j.jphotochem.2018.10.014https://www.sciencedirect.com/science/article/pii/S101060301831100625-33369
2019Lee, Byunghong; Ezhumalai, Yamuna; Lee, Woongkyu; Chen, Ming-Chou; Yeh, Chen-Yu; Marks, Tobin J.; Chang, Robert P. H.Cs2SnI6-Encapsulated Multidye-Sensitized All-Solid-State Solar CellsACS Applied Materials & Interfaces10.1021/acsami.8b19778https://doi.org/10.1021/acsami.8b1977821424-214342411
2016Molla, Md Zaman; Kawano, Minobu; Baranwal, Ajay K.; Pandey, Shyam S.; Ogomi, Yuhei; Ma, Tingli; Hayase, ShuziEnhancing the performance of transparent conductive oxide-less back contact dye-sensitized solar cells by facile diffusion of cobalt species through TiO2 nanoporesRSC Advances10.1039/C6RA04894Chttps://pubs.rsc.org/en/content/articlelanding/2016/ra/c6ra04894c33353-33360406
2022Zhang, Hai; Zhou, Jing; Zang, Xu-Feng; Hong, Yan-Ping; Chen, Zhen-EAn efficient strategy for designing high-performance DSSCs: Using the terminal auxiliary acceptor to improve electronic transitionsDyes and Pigments10.1016/j.dyepig.2022.110642https://www.sciencedirect.com/science/article/pii/S0143720822005642110642206
2018Hajizadeh, Fatemeh; Reisi-Vanani, Adel; Azar, Yavar T.Theoretical design of Zn-dithiaporphyrins as sensitizer for dye-sensitized solar cellsCurrent Applied Physics10.1016/j.cap.2018.06.011https://www.sciencedirect.com/science/article/pii/S15671739183017921122-11331018
2017Mendizabal, Fernando; Mera-Adasme, Ra?l; Xu, Wen-Hua; Sundholm, DageElectronic and optical properties of metalloporphyrins of zinc on TiO2 cluster in dye-sensitized solar-cells (DSSC). A quantum chemistry studyRSC Advances10.1039/C7RA08648Bhttps://pubs.rsc.org/en/content/articlelanding/2017/ra/c7ra08648b42677-42684687
2021Santos, F?tima; Hora, Carolina; Ivanou, Dzmitry; Mendes, Ad?lio M.Efficient Liquid-Junction Monolithic Cobalt-Mediated Dye-Sensitized Solar Cells for Solar and Artificial Light ConversionACS Applied Energy Materials10.1021/acsaem.1c00616https://doi.org/10.1021/acsaem.1c006165050-505854
2017Higashino, Tomohiro; Nimura, Shimpei; Sugiura, Kenichi; Kurumisawa, Yuma; Tsuji, Yukihiro; Imahori, HiroshiPhotovoltaic Properties and Long-Term Durability of Porphyrin-Sensitized Solar Cells with Silicon-Based Anchoring GroupsACS Omega10.1021/acsomega.7b01290https://doi.org/10.1021/acsomega.7b012906958-6967102
2014Molla, Md. Zaman; Mizukoshi, Norihiro; Furukawa, Hiroaki; Ogomi, Yuhei; Pandey, Shyam S.; Ma, Tingli; Hayase, ShuziTransparent conductive oxide-less back contact dye-sensitized solar cells using cobalt electrolyteProgress in Photovoltaics: Research and Applications10.1002/pip.2526https://onlinelibrary.wiley.com/doi/abs/10.1002/pip.25261100-1109923
2025Kodji, Nouake; , Souop Tala Foadin ,Crevain; , Mohammadou ,Sali; , Tchangnwa Nya ,Fridolin; and Ejuh, Geh WilsonImplementation of bridged copolymerisation to optimise the optical properties of porphyrin: applications in dye-sensitized solar cellsMolecular Physics10.1080/00268976.2024.2345727https://doi.org/10.1080/00268976.2024.2345727e23457271123
2023Liao, Jian-Ming; Chin, Yu-Kai; Wu, Yu-Ting; Chou, Hsien-HsinEffect of regio-specific arylamine substitution on novel ƒÎ-extended zinc salophen complexes: density functional and time-dependent density functional study on DSSC applicationsRSC Advances10.1039/D2RA07571Ghttps://pubs.rsc.org/en/content/articlelanding/2023/ra/d2ra07571g2501-2513413
2016Peng, Jia-De; Tseng, Chuan-Ming; Vittal, R.; Ho, Kuo-ChuanMesoporous anatase-TiO2 spheres consisting of nanosheets of exposed (001)-facets for [Co(byp)3]2+/3+ based dye-sensitized solar cellsNano Energy10.1016/j.nanoen.2016.01.025https://www.sciencedirect.com/science/article/pii/S2211285516000458136-14822

以下に、アップロードいただいたデータに基づき、物質・方法・新発見を中心にまとめ、雑誌名・年号も明記した要約(DSSC関連)を日本語と英語の両方でご提供します。


🧪 色素増感太陽電池(DSSC)研究の物質・方法・新発見の整理

🔬物質

  • 共通材料:ポルフィリン系色素(YD2-o-C8など)、Zn(II)/Ti(IV)ナフタレンフタロシアニン、A3B型ファロシアニン、サロフェン錯体、トロポロン、シラン系アンカー。
  • 電解質・添加剤:Co(bpy)₃²⁺/³⁺、CDCA(コアドソーバント)、TiO₂メソポーラス構造(アナターゼ型)。
  • 補助光吸収層:ZnPc, TiOPc とのカクテル構成や、Zn-salophenなどを用いた補助吸収色素。
  • 新規設計分子:架橋共重合体ポルフィリン、D-π-A構造の電子供与基/アクセプター修飾系。

⚙方法

  • 共感光色素法(co-sensitization):YD2-o-C8と他色素(例:ZnPc, TiOPc, ZS12)を特定比率で組合せ、広帯域吸収性とIPCE向上を達成(例:2025年, J. Photochem. Photobiol. A)。
  • アンカリング基の工夫:カルボン酸→シラン、トロポロンへの置換により長期耐久性やTiO₂表面との結合強度向上(2017年 ACS Omega, 2015年 Angew. Chem.)。
  • 量子化学解析:DFTおよびTD-DFTを用いた軌道解析や、電子注入・再生成エネルギーの定量評価(複数論文、例:2017年 Mol. Cryst. Liq. Cryst.)。
  • デバイス構成最適化:メソポーラスTiO₂の(001)面露出制御(2016年 Nano Energy)、TCOレス構造(2016年 RSC Adv.)など。

🌟新発見

  • 効率向上:YD2 + ZnPc系(3:1)で最大変換効率10.87%、TiOPc系で10.72%を達成(2025年, J. Photochem. Photobiol. A)。
  • 安定性と結合性:トロポロンやシランアンカーにより、YD2-o-C8よりも優れた長期安定性が確認(2015–2017)。
  • 吸収拡張・可視~近赤外対応:A3B型非対称ファロシアニンとYD2の組合せで、N719を上回る吸収帯域と性能(2025年 J. Photochem. Photobiol. A)。
  • ナノ構造の活用:アナターゼTiO₂球状構造と表面反射で光捕集性向上(2016年 Nano Energy)、コバルト系電解質との親和性向上。

🇬🇧 Summary in English (Materials / Methods / Key Findings)

🔬Materials

  • Common dyes: Porphyrins (YD2-o-C8), Zn/Ti-phthalocyanines, A3B-type dyes, Zn-salophen complexes, tropolone/silanized anchors.
  • Electrolytes & additives: Cobalt-based redox shuttles (Co(bpy)₃²⁺/³⁺), CDCA, anatase-type mesoporous TiO₂.
  • Novel molecules: Bridged porphyrin copolymers, D–π–A type sensitizers, phthalocyanine–porphyrin dye cocktails.

⚙Methods

  • Co-sensitization: Strategic dye pairing (e.g., YD2 + ZnPc or TiOPc in 3:1 ratio) achieved high efficiency and broad spectral response (2025, J. Photochem. Photobiol. A).
  • Anchoring optimization: Replacing conventional carboxylic acids with tropolone or silane improved dye stability and TiO₂ binding (2015–2017).
  • Theoretical approach: DFT/TD-DFT studies to optimize energy levels, transition characteristics, and charge dynamics (multiple papers).
  • Device innovations: Enhanced light harvesting via (001)-facet TiO₂ microspheres, and TCO-less back-contact DSSCs (2016, Nano Energy; RSC Advances).

🌟Key Findings

  • High efficiencies: Achieved PCE up to 10.87% with YD2:ZnPc (3:1), and 10.72% with YD2:TiOPc combinations (2025).
  • Enhanced stability: Tropolone and silane anchor groups provided superior long-term durability over YD2-o-C8.
  • Broader absorption: A3B ZnPc derivatives and porphyrin cocktails exceeded N719’s performance, extending into the NIR range.
  • Nanostructure benefits: Mesoporous TiO₂ with high (001) facet exposure enhanced dye coverage and reflectivity, boosting Jsc and Voc.

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