Insulated conjugated bimetallopolymer with sigmoidal response by dual self-controlling system as a biomimetic material.
Nat Commun. 2020 01 21;11(1):408
Authors: Masai H, Yokoyama T, Miyagishi HV, Liu M, Tachibana Y, Fujihara T, Tsuji Y, Terao J
DOI: 10.1038/s41467-019-14271-2
非平衡な外部刺激応答材料を「自律化」する
化学者のつぶやき – Chem-Station (ケムステ)
第2xx回のスポットライトリサーチは、東京大学大学院 総合文化研究科・正井宏 助教にお願いしました。 正井さんの所属する寺尾研究室では、ロタキサン構造で被覆した有機ポリマー型導線の創成と、新たな有機デバイスへの応用展開に […]
Who Hiroshi Masai, Takuya Yokoyama, Hiromichi V. Miyagishi, Maning Liu, Yasuhiro Tachibana, Tetsuaki Fujihara, Yasushi Tsuji & Jun Terao When 2020, January 21 Where Tokyo, Japan What an insulated conjugated bimetallopolymer exhibits phosphorescence in response to CO gas.
:the conjugated bimetallopolymer containing an insulated structure
:where the Pt(II) and Ru(II) complexes were polymerized with oligo(phenylene ethynylene) backbones and insulated by permethylated α-cyclodextrins.Why Provide routes for the development of higher-ordered artificial molecular systems bearing bioinspired responses with autonomous modulation. How *Activation of the system:
1st : the depolymerization of the non-radiative conjugated polymer to luminescent monomers
*2nd: the switch in the rate-determining step of the Ru complex.
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