Organic LED and 4,4′,4 ”-tris(N-(2-naphthyl)-N-phenylamino)triphenylamine
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Duan, LF; Wang, GH; Duan, Y; Lei, DL; Qian, FL; Yang, QM | Duan, Liangfei; Wang, Guanghua; Duan, Yu; Lei, Denglin; Qian, Fuli; Yang, Qiming | Design Simulation and Preparation of White OLED Microdisplay Based on Microcavity Structure Optimization | JOURNAL OF SPECTROSCOPY | English | Article | LIGHT-EMITTING DEVICES; EFFICIENCY ROLL-OFF; HIGHLY EFFICIENT; BLUE; STABILITY | White-light OLED devices play an important application in information display fields. Optical interference of the microcavity structure has an important effect on device performances. According to the design of the band structure, ITO/MoO3 composite films were used as the anode, and Mg : Ag (1%) composite films were prepared by coevaporation as the translucent cathode; CuPc was used as the hole injection layer and anode passivation layer, NPB as the hole transmission layer and yellow light main material, rubrene as yellow dopant material, ADN as blue light main material, DSA-Ph as blue dopant material, and TPBi and Alq3 as the electron transport layers. We realized the change of the microcavity structure by adjusting the thickness of each organic functional layer film and simulated and calculated the optimized thickness of each organic film layer and influence on OLED device performances using the SimOLED software system. The optimized OLED microdisplay structure is Si-(CMOS)/ITO (35 nm)/MoO3 (2 nm)/CuPc (5 nm)/2-TNATA (20 nm)/NPB (10 nm)/NPB : rubrene (1.5%)ADN : DSA-Ph (5%) (25 nm)/TPBi (15 nm)/Alq3 (1.2 nm)/Mg (13 nm) : Ag (1%). The optimized OLED microdisplay was prepared by the vacuum coating system, and the photoelectric performances of the OLED device were characterized by a spectral testing system consisting of the Photo Research PR655 spectrometer and Keithley 2400 program-controlled power supply. The effect of the microcavity structure on OLED device performances was studied. The results show that the variation of the film thickness of each organic functional layer has an important effect on the performances of OLED microdisplay, such as brightness and color coordinate, and the OLED microdisplay reaches a higher brightness of 3342 cd/m(2) under the normal working voltage at 5.0 V after the structure is optimized, with CIE coordinate (0.28, 0.37), which is closer to the energy point of standard white light. | [Duan, Liangfei; Wang, Guanghua; Duan, Yu; Lei, Denglin; Qian, Fuli; Yang, Qiming] Yunnan OLiGHTEK Optoelect Technol Co Ltd, Kunming 650214, Yunnan, Peoples R China | Duan, LF i˜A—’˜ŽÒjAYunnan OLiGHTEK Optoelect Technol Co Ltd, Kunming 650214, Yunnan, Peoples R China. | liangfeiduan1012@163.com | duan, liangfei/0000-0001-9981-1724 | Yunnan Fundamental Research Projects [2019-1-C-25318000002171]; Postgraduate Research Innovation Project of Yunnan University [2020174] | Yunnan Fundamental Research Projects; Postgraduate Research Innovation Project of Yunnan University | The authors gratefully acknowledge the financial support from Yunnan Fundamental Research Projects (2019-1-C-25318000002171) and Postgraduate Research Innovation Project of Yunnan University (2020174). | 23 | 3 | 7 | 2 | 62 | HINDAWI LTD | LONDON | ADAM HOUSE, 3RD FLR, 1 FITZROY SQ, LONDON, W1T 5HF, ENGLAND | 2314-4920 | 2314-4939 | J SPECTROSC | J. Spectrosc. | MAY 10 | 2021 | 2021 | 5529644 | 10.1155/2021/5529644 | http://dx.doi.org/10.1155/2021/5529644 | 8 | Biochemical Research Methods; Spectroscopy | Science Citation Index Expanded (SCI-EXPANDED) | Biochemistry & Molecular Biology; Spectroscopy | |||||||||||||||||||
Lee, S; Kim, B; Jung, H; Shin, H; Lee, H; Lee, J; Park, J | Lee, Suji; Kim, Beomjin; Jung, Hyocheol; Shin, Hwangyu; Lee, Hayoon; Lee, Jaehyun; Park, Jongwook | Synthesis and electroluminescence properties of new blue dual-core OLED emitters using bulky side chromophores | DYES AND PIGMENTS | English | Article | OLED; Electroluminescence; Blue emission; Fluorene; Carbazole; Bulky side group; Chromophores | LIGHT-EMITTING-DIODES; ANTHRACENE-DERIVATIVES; COLOR-PURITY; EFFICIENCY; POLYMERS; DEVICES | Using a 1-anthracen-9-yl-pyrene (AP) dual-core emitter, two new emitters of blue light, 1-spiro-9,9'-bifluoren-4-yl-6-(10-spiro-9,9'-bifluoren-4-yl-anthracen-9-yl)-pyrene (DSF-AP) and 1-[2-(9H-carbazol-9-yl)phenyl]-6-[2-(9H-carbazol-9-yl)phenyl-anthracen-9-yl]-pyrene (DCP-AP), were synthesized through boration and the Suzuki aryl-aryl coupling reaction. These two materials exhibited PLmax values at 443 nm and 448 nm in a chloroform solution, and at 458 nm and 463 nm in a thin-film state. EL devices with the synthesized compounds were fabricated in the following configuration: ITO/4,4',4 ''-tris(N-(2-naphthyl)-N-phenylamino)triphenylamine (2-TNATA) (60 nm)/N,N'-bis (naphthalene-1-yl)-N,N'-bis(phenyl)benzidine (NPB) (15 nm)/synthesized blue light-emitting materials (35 nm)/Tris-(8-hydroxyquinoline)aluminum (Alq(3)) (20 nm)/lithium fluoride (LiF) (1 nm)/Al (200 nm). Compared with the device made using an AP core lacking side groups, the device made with DCP-AP displayed 31% higher luminance efficiency (resulting in a value of 4.37 cd/A) and 32% higher power efficiency (to yield 1.93 lm/W), as well as a high external quantum efficiency (3.64%). (C) 2016 Elsevier Ltd. All rights reserved. | [Jung, Hyocheol; Lee, Hayoon; Park, Jongwook] Kyung Hee Univ, Dept Chem Engn, Yongin 17104, Gyeonggi Do, South Korea; [Lee, Suji; Shin, Hwangyu; Lee, Jaehyun] Catholic Univ Korea, Dept Chem, Bucheon 420743, South Korea; [Kim, Beomjin] Korea Res Inst Chem Technol, Res Ctr Green Fine Chem, Ulsan 681802, South Korea | Kyung Hee University; Catholic University of Korea; Korea Research Institute of Chemical Technology (KRICT) | Park, J i˜A—’˜ŽÒjAKyung Hee Univ, Dept Chem Engn, Yongin 17104, Gyeonggi Do, South Korea. | hahapark@catholic.ac.kr | Fundamental R&D Program for Core Technology of Materials - Ministry of Trade, Industry and Energy, Republic of Korea [10050215]; Technology Development Program for Strategic Core Materials - Ministry of Trade, Industry & Energy, Republic of Korea [10047758] | Fundamental R&D Program for Core Technology of Materials - Ministry of Trade, Industry and Energy, Republic of Korea; Technology Development Program for Strategic Core Materials - Ministry of Trade, Industry & Energy, Republic of Korea | This research was supported by a grant from the Fundamental R&D Program for Core Technology of Materials funded by the Ministry of Trade, Industry and Energy, Republic of Korea (Project No. 10050215). This research was supported by a grant from the Technology Development Program for Strategic Core Materials funded by the Ministry of Trade, Industry & Energy, Republic of Korea (Project No. 10047758). | 24 | 19 | 19 | 0 | 145 | ELSEVIER SCI LTD | OXFORD | THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND | 0143-7208 | 1873-3743 | DYES PIGMENTS | Dyes Pigment. | JAN | 2017 | 136 | 255 | 261 | 10.1016/j.dyepig.2016.08.010 | http://dx.doi.org/10.1016/j.dyepig.2016.08.010 | 7 | Chemistry, Applied; Engineering, Chemical; Materials Science, Textiles | Science Citation Index Expanded (SCI-EXPANDED) | Chemistry; Engineering; Materials Science | |||||||||||||||||
Shin, H; Kang, H; Kim, JH; Wang, YF; Kim, S; Kay, KY; Park, J | Shin, Hwangyu; Kang, Hyeonmi; Kim, Jong-Hyung; Wang, Yun-Fan; Kim, Seungho; Kay, Kwang-Yol; Park, Jongwook | Synthesis and Electroluminescence Property of New Hexaphenyl Benzene Derivatives Including Emitting Core for OLED | JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY | English | Article | OLED; Hexaphenylbenzene; Anthracene; Pyrene; Triphenylamine | HOST MATERIALS | Three new emitting compounds of 5P-2TPA, 5P-2An and 5P-2Py for OLED based on hexaphenyl benzene moiety were synthesized. Physical properties were systematically examined by the change of the substitution groups of the synthesized materials. Photoluminescence (PL) spectrum of the synthesized materials showed maximum emitting wavelengths of about 437 similar to 488 nm in solution state and 457 similar to 516 nm in film state, indicating blue emission color. OLED devices were fabricated by the synthesized compounds using vacuum deposition process as an emitting layer. Device structure was ITO/2-TNATA 60 nm/NPB 15 nm/EML 35 nm/TPBi 20 nm/LiF 1 nm/AI 200 nm. External quantum efficiencies and CIE values of 5P-2TPA, 5P-2An and 5P-2Py were 3.34, 1.06 and 2.06% and (0.14, 0.12), (0.23, 0.45) and (0.24, 0.45), respectively. The three compounds exhibited thermal stablility with high T-d of 426 degrees C, 449 degrees C and 467 degrees C. | [Shin, Hwangyu; Kang, Hyeonmi; Kim, Seungho; Park, Jongwook] Catholic Univ Korea, Dept Chem, Bucheon 420743, South Korea; [Kim, Jong-Hyung; Wang, Yun-Fan; Kay, Kwang-Yol] Ajou Univ, Dept Mol Sci & Technol, Suwon 443749, South Korea | Catholic University of Korea; Ajou University | Kay, KY i˜A—’˜ŽÒjAAjou Univ, Dept Mol Sci & Technol, Suwon 443749, South Korea. | Fundamental R&D Program for Core Technology of Materials - Ministry of Trade, Industry and Energy, Republic of Korea [10050215] | Fundamental R&D Program for Core Technology of Materials - Ministry of Trade, Industry and Energy, Republic of Korea | This research was supported by a grant from the Fundamental R&D Program for Core Technology of Materials funded by the Ministry of Trade, Industry and Energy, Republic of Korea (Project No. 10050215). | 16 | 2 | 2 | 0 | 23 | AMER SCIENTIFIC PUBLISHERS | VALENCIA | 26650 THE OLD RD, STE 208, VALENCIA, CA 91381-0751 USA | 1533-4880 | 1533-4899 | J NANOSCI NANOTECHNO | J. Nanosci. Nanotechnol. | OCT | 2015 | 15 | 10 | SI | 8289 | 8294 | 10.1166/jnn.2015.11260 | http://dx.doi.org/10.1166/jnn.2015.11260 | 6 | Chemistry, Multidisciplinary; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary; Physics, Applied; Physics, Condensed Matter | Science Citation Index Expanded (SCI-EXPANDED) | Chemistry; Science & Technology - Other Topics; Materials Science; Physics | ||||||||||||||||
Duan, LF; Yang, HQ; Wang, GH; Duan, Y | Duan, Liangfei; Yang, Huiqin; Wang, Guanghua; Duan, Yu | Preparation of 8-hydroxyquinoline aluminum nanomaterials to enhance properties for green organic light-emitting diode devices | JOURNAL OF THE SOCIETY FOR INFORMATION DISPLAY | English | Article | Alq3; green OLED devices; molecular self-assembly; nanostructure; physical vapor deposition | Tris(8-hydroquinoline) aluminum (Alq3) plays an important role in the applications of green organic light-emitting diodes (OLEDs). In this paper, Alq3 nanofilms were prepared on glass substrates by physical vapor deposition system with different surface states. The structures and morphologies of Alq3 nanofilms were characterized by X-ray diffractometer and scanning electron microscope. Alq3 nanomaterials were used as the main luminescent material for green OLED devices. The structure of the green OLED is Mo/2-TNATA (20 nm)/NPB (10 nm)/Alq3 (25 nm):Ir(ppy)(3) (5%)/Bphen (10 nm)/LiF (5 nm)/Mg:Ag (10%) (10 nm). The photoelectric properties of green OLED devices were characterized by the system of Photo Research PR655 spectrometer. The results show that the weak interactions among Alq3 molecules such as pi-pi bond interactions and van der Waals forces caused molecules self-assembling into nanospheres, nanospherical chains, nanowires, or nanotubes in physical vapor deposition system. Precise surface state control of Alq3 nanomaterials can be realized by controlling the deposition temperature, thus, to enhance properties for green OLED displays. It is found that among different morphologies, Alq3 nanotubes have been proved to be the best green OLED devices with the brightness of 11,490 cd/m(2), CIE (3358, 0.6302) at 5 V, and the current efficiency is 20.24 cd/A. | [Duan, Liangfei] Yunnan Univ, Int Joint Res Ctr Optoelect & Energy Mat, Sch Mat & Energy, Yunnan Key Lab Micronano Mat & Technol, Kunming 650091, Yunnan, Peoples R China; [Yang, Huiqin] Yunnan Normal Univ, Sch Energy & Environm Sci, Kunming, Yunnan, Peoples R China; [Wang, Guanghua; Duan, Yu] Yunnan OLiGHTEK Optoelect Technol Co Ltd, Res & Dev Dept, Kunming, Yunnan, Peoples R China | Yunnan University; Yunnan Normal University | Duan, LF i˜A—’˜ŽÒjAYunnan Univ, Int Joint Res Ctr Optoelect & Energy Mat, Sch Mat & Energy, Yunnan Key Lab Micronano Mat & Technol, Kunming 650091, Yunnan, Peoples R China. | liangfeiduan1012@163.com | yang, hq/LDF-2209-2024; DUAN, YU/JXY-8226-2024 | Yunnan Provincial Fundamental Research Foundation [2019-1-C-25318000002171]; Postgraduate Research Innovation Project of Yunnan University [2020174] | Yunnan Provincial Fundamental Research Foundation; Postgraduate Research Innovation Project of Yunnan University | The authors gratefully acknowledge the Yunnan Provincial Fundamental Research Foundation (2019-1-C-25318000002171) and Postgraduate Research Innovation Project of Yunnan University (2020174). | 31 | 5 | 5 | 3 | 57 | WILEY | HOBOKEN | 111 RIVER ST, HOBOKEN 07030-5774, NJ USA | 1071-0922 | 1938-3657 | J SOC INF DISPLAY | J. Soc. Inf. Disp. | JUN | 2021 | 29 | 6 | 466 | 475 | 10.1002/jsid.986 | http://dx.doi.org/10.1002/jsid.986 | JAN 2021 | 10 | Engineering, Electrical & Electronic; Materials Science, Multidisciplinary; Optics; Physics, Applied | Science Citation Index Expanded (SCI-EXPANDED) | Engineering; Materials Science; Optics; Physics | |||||||||||||||
Lee, SB; Park, SN; Kim, C; Lee, HW; Lee, HW; Kim, YK; Yoon, SS | Lee, Seul Bee; Park, Soo Na; Kim, Chanwoo; Lee, Hyun Woo; Lee, Ho Won; Kim, Young Kwan; Yoon, Seung Soo | Synthesis and electroluminescent properties of 9,10-diphenylanthracene containing 9H-carbazole derivatives for blue organic light-emitting diodes | SYNTHETIC METALS | English | Article | Blue OLED; Anthracene; Carbazole; Buchwald-Hartwig cross-coupling reactions | HIGHLY EFFICIENT; MOLECULES; LAYER | Four novel molecules, 9-(9,10-diphenylanthracen-3-yl)-9H-carbazole (1), 7-(9,10-diphenylanthracen-3-yl)-7H-benzo[c]carbazole (2), 7-(9,10-diphenylanthracen-3-yl)-7H-benzo[e]pyrido[3,2-b]indole (3), 7-(9,10-diphenyl-2-(7H-benzo[e]pyrido[3,2-b]indol-7-yl)anthracen-6-yl)-7H-benzo[e]pyrido[3,2-b]indole (4), based on 9,10-diphenylanthracene with carbazole derivatives, were designed and synthesized via BuchwaldHartwig cross-coupling reactions. Multilayer OLED devices were fabricated with the following device structure: ITO/2-TNATA (60 nm)/NPB (20 nm)/alpha,beta-ADN:blue dopant materials (10%, 30 nm)/DNAB (30 nm)/Liq:Al. Among those, the device using 1 exhibited the efficient blue emission with a luminous efficiency of 4.56 cd/A, power efficiency of 1.95 lm/W, an external quantum efficiency of 3.42%, and CIE x,y coordinates of (0.15, 0.17) at 20 mA/cm(2), respectively. (C) 2015 Elsevier B.V. All rights reserved. | [Lee, Seul Bee; Park, Soo Na; Kim, Chanwoo; Lee, Hyun Woo; Yoon, Seung Soo] Sungkyunkwan Univ, Dept Chem, Suwon 440746, South Korea; [Lee, Ho Won; Kim, Young Kwan] Hongik Univ, Dept Informat Display, Seoul 121791, South Korea | Sungkyunkwan University (SKKU); Hongik University | Yoon, SS i˜A—’˜ŽÒjASungkyunkwan Univ, Dept Chem, Suwon 440746, South Korea. | kimyk@wow.hongik.ac.kr; ssyoon@skku.edu | Samsung Display and Basic Science Research Program through the NRF - Ministry of Education, Science and Technology [NRF-2013R1A1A2A10008105] | Samsung Display and Basic Science Research Program through the NRF - Ministry of Education, Science and Technology | This research was supported by the Samsung Display and Basic Science Research Program through the NRF funded by the Ministry of Education, Science and Technology (NRF-2013R1A1A2A10008105). | 17 | 26 | 26 | 5 | 78 | ELSEVIER SCIENCE SA | LAUSANNE | PO BOX 564, 1001 LAUSANNE, SWITZERLAND | 0379-6779 | SYNTHETIC MET | Synth. Met. | MAY | 2015 | 203 | 174 | 179 | 10.1016/j.synthmet.2015.02.037 | http://dx.doi.org/10.1016/j.synthmet.2015.02.037 | 6 | Materials Science, Multidisciplinary; Physics, Condensed Matter; Polymer Science | Science Citation Index Expanded (SCI-EXPANDED) | Materials Science; Physics; Polymer Science | ||||||||||||||||||
Kang, SK; Woo, J; Lee, SE; Kim, YK; Yoon, SS | Kang, Soo Kyung; Woo, Jeongkyu; Lee, Song Eun; Kim, Young Kwan; Yoon, Seung Soo | Organic Light-Emitting Diodes based on Benzo[q]quinoline Derivatives | MOLECULAR CRYSTALS AND LIQUID CRYSTALS | English | Article; Proceedings Paper | 30th Korea-Japan Forum (KJF) International Conference on Organic Materials for Electronics and Photonics (KJF-ICOMEP) | SEP 04-07, 2018 | Gifu, JAPAN | Korea Japan Forum,Gifu Convent & Visitors Bur,Tohoko Univ, Inst Multidisciplinary Res Adv Mat | OLED; benzo[q]quinoline derivatives; Electroluminescence | EMISSION; INTERFACE; EXCIMER | In this study, we synthesized two emitting materials based on benzo[q]quinoline derivatives. OLED devices using these materials were facricated in the following sequence;ITO(180nm)/4,4',4''-Tris[2-naphthyl(phenyl)amino]triphenylamine(2-TNATA)(30nm)/N,N'-di(1-naphthyl)-N,N'-diphenyl-(1,1'-biphenyl)-4,4'-diamine(NPB)(20nm)/Emitting materials(30nm)/4,7-diphenyl-1,10-phenanthroline (Bphen)(30nm)/Liq(2nm)/Al(100nm). Particularly, a device using 2,4-di(naphtalene-1-yl)benzo[q]quinoline as an emitter exhibited the efficient emission with a luminous efficiency, a power efficiency, and exteranl quantum efficiency of, and the CIE coordinates of 2.91cd/A, 0.99lm/W, 0.90% at 20mA/cm(2), and (0.33, 0.55) at 1000cd/m(2), respectively. Interestingly, emissions from electromers and electroplexes were shown to be crucial role in electroluminescences from benzo[q]quinoline derivatives | [Kang, Soo Kyung; Woo, Jeongkyu; Yoon, Seung Soo] Sungkyunkwan Univ, Dept Chem, Suwon 440746, Kyeonggi Do, South Korea; [Lee, Song Eun; Kim, Young Kwan] Hongik Univ, Dept Informat Display, Seoul 121791, South Korea | Sungkyunkwan University (SKKU); Hongik University | Yoon, SS i˜A—’˜ŽÒjASungkyunkwan Univ, Dept Chem, Suwon 440746, Kyeonggi Do, South Korea.;Kim, YK i˜A—’˜ŽÒjAHongik Univ, Seoul 121791, South Korea. | kimyk@hongik.ac.kr; ssyoon@skku.edu | Samsung display | Samsung display(Samsung) | This research was supported by Samsung display. | 18 | 8 | 9 | 0 | 6 | TAYLOR & FRANCIS LTD | ABINGDON | 2-4 PARK SQUARE, MILTON PARK, ABINGDON OR14 4RN, OXON, ENGLAND | 1542-1406 | 1563-5287 | MOL CRYST LIQ CRYST | Mol. Cryst. Liquid Cryst. | MAY 24 | 2019 | 685 | 1 | SI | 114 | 123 | 10.1080/15421406.2019.1645470 | http://dx.doi.org/10.1080/15421406.2019.1645470 | 10 | Chemistry, Multidisciplinary; Crystallography; Materials Science, Multidisciplinary | Science Citation Index Expanded (SCI-EXPANDED); Conference Proceedings Citation Index - Science (CPCI-S) | Chemistry; Crystallography; Materials Science | |||||||||||
Moon, J; Lee, J; Kim, KJ; Lee, H; Kim, YK; Yoon, SS | Moon, Junyoung; Lee, Jinho; Kim, Ki Ju; Lee, Hakjun; Kim, Young Kwan; Yoon, Seung Soo | Blue Fluorescent Organic Light-Emitting Diodes Using 11,11-Dimethy1-3-(10-phenylanthracen-9-yl)-11H-Indeno[1,2-b]Quinoline Derivatives | JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY | English | Article | Organic Light-Emitting Diode; Blue Fluorescence Material; Indenoquinoline | EFFICIENCY | In this study, we designed and synthesized two blue fluorescence materials using phenylanthracene-substituted-indenoquinoline derivatives by Suzuki coupling reaction for organic light-emitting diodes (OLEDs). In order to study their electroluminescent properties, we fabricated the OLED devices using these two materials as emissive layer (EML) with the following sequence: indium-tin-oxide (ITO, 180 nm)/4,4',4''-tris[2-naphthyl(phenyl)-amino]triphenylamine (2-TNATA, 30 nm)/N, N'-diphenyl-N, N'-(2-napthyl)-(1,1'-phenyl)-4,4'-diamine (NPB, 20 nm)/Blue emitting materials (20 nm)/4,7-Diphenyl-1,10-phenanthroline (Bphen, 30 nm)/lithium quinolate (Liq, 2 nm)/Al (100 nm). In particular, a device using 11,11-dimethyl-3-(10-phenylanthracen-9-yl)-11H-Indeno[1,2-b]quinoline in emitting layer showed luminous efficiency, power efficiency, and external quantum efficiency of 2.18 cd/A, 1.10 Im/W, 2.20% at 20 mA/cm(2), respectively, with Commission Internationale d'Enclairage (CIE) coordinates of (0.15, 0.11) at 8.0 V. | [Moon, Junyoung; Lee, Jinho; Yoon, Seung Soo] Sungkyunkwan Univ, Dept Chem, Suwon 440746, South Korea; [Kim, Ki Ju; Lee, Hakjun; Kim, Young Kwan] Hongik Univ, Dept Informat Display, Seoul 121791, South Korea | Sungkyunkwan University (SKKU); Hongik University | Yoon, SS i˜A—’˜ŽÒjASungkyunkwan Univ, Dept Chem, Suwon 440746, South Korea.;Kim, YK i˜A—’˜ŽÒjAHongik Univ, Dept Informat Display, Seoul 121791, South Korea. | Samsung Display and Basic Science Research Program through the NRF - Ministry of Education, Science and Technology [NRF-2015R1A6A1A03031833] | Samsung Display and Basic Science Research Program through the NRF - Ministry of Education, Science and Technology | This research was supported by Samsung Display and Basic Science Research Program through the NRF funded by the Ministry of Education, Science and Technology (NRF-2015R1A6A1A03031833). | 19 | 1 | 1 | 1 | 115 | AMER SCIENTIFIC PUBLISHERS | VALENCIA | 26650 THE OLD RD, STE 208, VALENCIA, CA 91381-0751 USA | 1533-4880 | 1533-4899 | J NANOSCI NANOTECHNO | J. Nanosci. Nanotechnol. | AUG | 2020 | 20 | 8 | 4652 | 4656 | 10.1166/jnn.2020.17824 | http://dx.doi.org/10.1166/jnn.2020.17824 | 5 | Chemistry, Multidisciplinary; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary; Physics, Applied; Physics, Condensed Matter | Science Citation Index Expanded (SCI-EXPANDED) | Chemistry; Science & Technology - Other Topics; Materials Science; Physics | |||||||||||||||||
Kang, S; Lee, H; Kim, B; Park, Y; Park, J | Kang, Seokwoo; Lee, Hayoon; Kim, Beomjin; Park, Youngil; Park, Jongwook | Synthesis and Property of New Propeller Shaped Emitting Materials for Organic Light-Emitting Devices | JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY | English | Article | OLEDs; Propeller Shaped Emitting Materials | ELECTROLUMINESCENCE PROPERTIES; BLUE; EFFICIENCY | New propeller type emitting compound, namely 3,6-di-anthracen-9-yl-9,10-bis-(4-anthracen-9-yl-phenyl)-phenanthrene[TAnDAP] and 3,6-bis-(10-phenyl-anthracen-9-yl)-9,10-bis-[4-(10-phenylanthracen-9-yl)-phenyl]-phenanthrene [TAnPDAP] were synthesized through Suzuki and McMurry reactions. We investigated their physical properties such as optical, electrochemical, and electroluminescent properties. The two compounds were used as an emitting layer in OLED devices: ITO/2-TNATA (60 nm)/NPB (15 nm)/non-doped: TAnDAP or TAnPDAP (35 nm)/Alq3 (20 nm)/LiF (1 nm)/Al (200 nm). The TAnDAP OLED device showed C.I.E. value of (0.28, 0.41) and luminance efficiency of 3.81 cd/A at 10 mA/cm(2). The TAnPDAP device showed C.I.E. value of (0.20, 0.27) and high luminance efficiency of 5.40 cd/A at 10 mA/cm(2). TAnPDAP was found to show better luminance efficiency and C.I.E. value than TAnDAP because it has a bulky 9-phenylanthracene. | [Kang, Seokwoo; Lee, Hayoon; Kim, Beomjin; Park, Jongwook] Catholic Univ Korea, Dept Chem, Bucheon 420743, South Korea; [Park, Youngil] Korea Res Inst Chem Technol, Div Ulsan Res, Ulsan 681802, South Korea; [Park, Youngil] Korea Res Inst Chem Technol, Res Ctr Green Fine Chem, Div Ulsan Res & Business Dev, Ulsan 681802, South Korea | Catholic University of Korea; Korea Research Institute of Chemical Technology (KRICT); Korea Research Institute of Chemical Technology (KRICT) | Park, J i˜A—’˜ŽÒjACatholic Univ Korea, Dept Chem, Bucheon 420743, South Korea. | National Research Foundation of Korea (NRF) - Korean government (MEST) [2012001846]; Global Collaborative R&D Project by the Ministry of Trade, Industry and Energy (The Korea Institute for the Advancement of Technology) [N0000903] | National Research Foundation of Korea (NRF) - Korean government (MEST)(Ministry of Education, Science & Technology (MEST), Republic of KoreaNational Research Foundation of KoreaKorean Government); Global Collaborative R&D Project by the Ministry of Trade, Industry and Energy (The Korea Institute for the Advancement of Technology) | This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korean government (MEST) (No. 2012001846). This research was supported by a grant from Global Collaborative R&D Project by the Ministry of Trade, Industry and Energy (The Korea Institute for the Advancement of Technology) (No. N0000903). | 12 | 3 | 3 | 0 | 34 | AMER SCIENTIFIC PUBLISHERS | VALENCIA | 26650 THE OLD RD, STE 208, VALENCIA, CA 91381-0751 USA | 1533-4880 | 1533-4899 | J NANOSCI NANOTECHNO | J. Nanosci. Nanotechnol. | MAR | 2016 | 16 | 3 | 3102 | 3105 | 10.1166/jnn.2016.11055 | http://dx.doi.org/10.1166/jnn.2016.11055 | 4 | Chemistry, Multidisciplinary; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary; Physics, Applied; Physics, Condensed Matter | Science Citation Index Expanded (SCI-EXPANDED) | Chemistry; Science & Technology - Other Topics; Materials Science; Physics | |||||||||||||||||
Lee, J; Kim, B; Park, J | Lee, Jaehyun; Kim, Beomjin; Park, Jongwook | Excimer Formation Promoted by Steric Hindrance in Dual Core Chromophore for Organic Light-Emitting Diodes Emitters | JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY | English | Article | Excimer; Intermolecular Interaction; OLEDs | EMISSION | A new dual core derivative of 1-(3,5-dipyrid-3-yl-phenyl)-6-(10-(3,5-dipyrid-3-yl-phenyl)-anthracen9- yl)-pyrene (3P-AP-3P) was synthesized by introducing pyridine groups. 1-[1,1'; 3',1 ''] Terphenyl-5'-yl-6-(10-[1,1'; 3',1 ''] terphenyl-5'-yl-anthracen-9-yl)-pyrene (TP-AP-TP) was used to compare with 3P-AP-3P. Unlike TP-AP-TP, 3P-AP-3P exhibited an excimer emission at 602 nm by introducing pyridine groups despite its highly twisted core. Two materials were used as emitting layer (EML) in OLED devices: ITO/2-TNATA (60 nm)/NPB (15 nm)/the synthesized materials (35 nm)/Alq(3) (20 nm)/LiF (1 nm)/Al (200 nm). The 3P-AP-3P device exhibited EL maximum values at 463 nm and 601 nm. | [Lee, Jaehyun; Park, Jongwook] Catholic Univ Korea, Dept Chem, Bucheon 420743, South Korea; [Kim, Beomjin] Korea Res Inst Chem Technol, Res Ctr Green Fine Chem, Ulsan 681802, South Korea | Catholic University of Korea; Korea Research Institute of Chemical Technology (KRICT) | Park, J i˜A—’˜ŽÒjACatholic Univ Korea, Dept Chem, Bucheon 420743, South Korea. | Fundamental R&D Program for Core Technology of Materials - Ministry of Trade, Industry and Energy, Republic of Korea [10050215] | Fundamental R&D Program for Core Technology of Materials - Ministry of Trade, Industry and Energy, Republic of Korea | This research was supported by a grant from the Fundamental R&D Program for Core Technology of Materials funded by the Ministry of Trade, Industry and Energy, Republic of Korea (Project No. 10050215). | 9 | 3 | 3 | 0 | 25 | AMER SCIENTIFIC PUBLISHERS | VALENCIA | 26650 THE OLD RD, STE 208, VALENCIA, CA 91381-0751 USA | 1533-4880 | 1533-4899 | J NANOSCI NANOTECHNO | J. Nanosci. Nanotechnol. | AUG | 2016 | 16 | 8 | 8854 | 8857 | 10.1166/jnn.2016.12479 | http://dx.doi.org/10.1166/jnn.2016.12479 | 4 | Chemistry, Multidisciplinary; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary; Physics, Applied; Physics, Condensed Matter | Science Citation Index Expanded (SCI-EXPANDED) | Chemistry; Science & Technology - Other Topics; Materials Science; Physics | |||||||||||||||||
Kang, S; Lee, H; Kim, B; Kang, H; Park, J | Kang, Seokwoo; Lee, Hayoon; Kim, Beomjin; Kang, Hyeonmi; Park, Jongwook | Synthesis and Property of New Blue Emitting Materials with Bulky Side Group | MOLECULAR CRYSTALS AND LIQUID CRYSTALS | English | Article; Proceedings Paper | 18TH INTERNATIONAL SYMPOSIUM ON ADVANCED DISPLAY MATERIALS AND DEVICES (ADMD) | JUL 23-25, 2014 | Sendai, JAPAN | SENDAI Tourism & Convention BUR,Chem Soc Japan,Japanese Liquid Crystal Soc,IMRAM Tohoku Univ | OLEDs; Blue materials; Bulky Side group; Anthracene | PHTHALOCYANINE THIN-FILMS; COPPER PHTHALOCYANINE; ELECTROLUMINESCENCE; DERIVATIVES; EMISSION; TRANSISTORS; EFFICIENCY; POLYMERS; ENERGY; CHAIN | Two emitting compounds, 9,10-bis-[1,1;3,1]terphenyl-5-yl-1,5-di-o-tolyl-anthracene [TP-DTA-TP] and 9,10-bis-phenyl[1,1;3,1]triphenyl-5-yl-1,5-di-o-tolyl-anthracene [TPB-DTA-TPB] based on new twisted core moiety were synthesized through boration, Suzuki reaction, and Sandmeyer reactions. EL performance was improved by varying the chemical structure of the side group. Physical properties such as optical, electrochemical, and electroluminescent properties were investigated. Synthesized compounds were used as an EML in OLED device: ITO / 2-TNATA (60nm) / NPB (15nm)/ TP-DTA-TP or TPB-DTA-TPB (35nm) / Alq3 (20nm) / LiF (1nm) / Al (200nm). It was found that TPB-DTA-TPB showed higher luminance efficiency and better C.I.E. value than TP-DTA-TP device. | [Kang, Seokwoo; Lee, Hayoon; Kim, Beomjin; Kang, Hyeonmi; Park, Jongwook] Catholic Univ Korea, Dept Chem, Bucheon, South Korea | Catholic University of Korea | Park, J i˜A—’˜ŽÒjACatholic Univ Korea, Dept Chem, 43-1 Yeokgok, Wonmi, Bucheon, South Korea. | hahapark@catholic.ac.kr | Fundamental R&D Program for Core Technology of Materials - Ministry of Trade, Industry and Energy, Republic of Korea [10050215] | Fundamental R&D Program for Core Technology of Materials - Ministry of Trade, Industry and Energy, Republic of Korea | This research was supported by a grant from the Fundamental R&D Program for Core Technology of Materials funded by the Ministry of Trade, Industry and Energy, Republic of Korea (Project No. 10050215). | 20 | 5 | 5 | 1 | 29 | TAYLOR & FRANCIS LTD | ABINGDON | 2-4 PARK SQUARE, MILTON PARK, ABINGDON OR14 4RN, OXON, ENGLAND | 1542-1406 | 1563-5287 | MOL CRYST LIQ CRYST | Mol. Cryst. Liquid Cryst. | SEP 2 | 2015 | 618 | 1 | SI | 66 | 73 | 10.1080/15421406.2015.1076296 | http://dx.doi.org/10.1080/15421406.2015.1076296 | 8 | Chemistry, Multidisciplinary; Crystallography; Materials Science, Multidisciplinary | Science Citation Index Expanded (SCI-EXPANDED); Conference Proceedings Citation Index - Science (CPCI-S) | Chemistry; Crystallography; Materials Science | |||||||||||
Kang, S; Lee, H; Jung, H; Shin, D; Park, M; Kay, KY; Park, J | Kang, Seokwoo; Lee, Hayoon; Jung, Hyocheol; Shin, Donghee; Park, Miyeon; Kay, Kwang-Yol; Park, Jongwook | Synthesis and Electroluminescence Properties of New Type Multi-Chromophore Emitting Materials for Organic Light-Emitting Diodes | JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY | English | Article | OLEDs; Emitting Materials; Multi-Chromophore | BLUE; DEVICE; DESIGN | New three emitting compounds, AK-1, AK-2 and AK-3 including diazocine moiety were synthesized through Suzuki-coupling reaction. Physical properties such as optical, electroluminescent properties were investigated. UV-visible spectrum of AK-1, AK-2 and AK-3 in film state showed maximum 392, 393 and 401 nm. PL spectrum of AK-1, AK-2 and AK-3 showed maximum emission wavelength of 472, 473 and 435 nm. Three compounds were used as EML in OLED device: ITO/2-TNATA (60 nm)/NPB (15 nm)/EML (35 nm)/Alq(3) (20 nm)/LiF (1 nm)/Al (200 nm). AK-3 OLED device showed C.I.E value of (0.18, 0.26) and luminance efficiency of 0.51 cd/A at 10 mA/cm(2). New derivatives including diazocine moiety were introduced as OLED emitting material and the EL efficiency was increased by the proper combination of core and side group. | [Kang, Seokwoo; Lee, Hayoon; Jung, Hyocheol; Park, Jongwook] Kyunghee Univ Korea, Dept Chem Engn, Seoul 17104, Gyeonggi Do, South Korea; [Park, Miyeon; Kay, Kwang-Yol] G OLED Co Ltd, R&D Ctr, Yeongtong Ro 323-38, Suwon 16676, South Korea; [Kay, Kwang-Yol] Ajou Univ, Dept Mol Sci & Technol, Suwon 16499, South Korea | Ajou University | Park, J i˜A—’˜ŽÒjAKyunghee Univ Korea, Dept Chem Engn, Seoul 17104, Gyeonggi Do, South Korea.;Kay, KY i˜A—’˜ŽÒjAG OLED Co Ltd, R&D Ctr, Yeongtong Ro 323-38, Suwon 16676, South Korea.;Kay, KY i˜A—’˜ŽÒjAAjou Univ, Dept Mol Sci & Technol, Suwon 16499, South Korea. | Industrial Core Technology Development Program for Strategic Core Materials - Ministry of Trade, Industry and Energy, Republic of Korea [10047758]; Basic Science Research Program through the National Research Foundation of Korea (NRF) - Ministry of Education [2016R1D1A1B03931477]; Technological innovation R&D program of SMBA [S2359547] | Industrial Core Technology Development Program for Strategic Core Materials - Ministry of Trade, Industry and Energy, Republic of Korea; Basic Science Research Program through the National Research Foundation of Korea (NRF) - Ministry of Education(National Research Foundation of KoreaMinistry of Education (MOE), Republic of Korea); Technological innovation R&D program of SMBA(Small & Medium Business Administration (SMBA), Republic of Korea) | This research was supported by a grant from the Industrial Core Technology Development Program for Strategic Core Materials funded by the Ministry of Trade, Industry and Energy, Republic of Korea (Project No. 10047758). This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (No. 2016R1D1A1B03931477). This work was partly supported by the Technological innovation R&D program of SMBA [S2359547]. | 6 | 2 | 2 | 0 | 20 | AMER SCIENTIFIC PUBLISHERS | VALENCIA | 26650 THE OLD RD, STE 208, VALENCIA, CA 91381-0751 USA | 1533-4880 | 1533-4899 | J NANOSCI NANOTECHNO | J. Nanosci. Nanotechnol. | MAR | 2018 | 18 | 3 | 2162 | 2165 | 10.1166/jnn.2018.14947 | http://dx.doi.org/10.1166/jnn.2018.14947 | 4 | Chemistry, Multidisciplinary; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary; Physics, Applied; Physics, Condensed Matter | Science Citation Index Expanded (SCI-EXPANDED) | Chemistry; Science & Technology - Other Topics; Materials Science; Physics | |||||||||||||||||
Ryu, J; Jo, MJ; Jung, H; Lee, H; Shin, D; Park, M; Kay, KY; Park, J | Ryu, Jaemin; Jo, Min-Jin; Jung, Hyocheol; Lee, Hayoon; Shin, Donghee; Park, Miyeon; Kay, Kwang-Yol; Park, Jongwook | Synthesis and electroluminescent properties of diazocine derivatives | MOLECULAR CRYSTALS AND LIQUID CRYSTALS | English | Article | Diazocine; electroluminescence; emitting material; fluorescence; OLED | DIODES | Four new diazocine derivatives including anthracene moiety, 2,8-Bis-[3-(10-naphthalen-2-yl-anthracen-9-yl)-phenyl]-6H,12H-5, 11-methano-dibenzo[b,f][1,5]diazocine(AK14), 2,8-Bis-[2-(10-naphthalen-2-yl-anthrac-en-9-yl)-phenyl]-6H,12H-5,11-methano-dibenzo[b,f][1,5]diazocine(AK15), 2,8-Bis-[4-(10-phenyl-anthracen-9-yl)-phenyl]-6H,12H-5,11-methano-dib-enzo[b,f][1,5]diazocine(AK20), 2,8-Bis-[2-(10-phenyl-anthracen-9-yl)-ph-enyl]-6H,12H-5,11-methano-dibenzo[b,f][1,5]diazocine(AK21) were synth-esized. Those materials exhibited photoluminescence (PL) maximum value of about 411 approximate to 428nm in solution state and 429 approximate to 483nm in film state, respectively.Four compounds were used as EML in OLED device: ITO / 2-TNATA (60nm) / NPB (15nm) / EML (35nm) / Alq3 (20nm) / LiF / Al. OLED devices, fabricated by AK14, AK20 and AK21, showed the current efficiency with 2.16cd/A, 0.28cd/A and 1.56cd/A. The OLED device, fabricated by AK15, showed the best performance with 2.83cd/A, 1.25lm/W and CIE(x,y) = (0.16, 0.23). | [Ryu, Jaemin; Jung, Hyocheol; Lee, Hayoon; Park, Jongwook] Kyung Hee Univ, Dept Chem Engn, 1732 Deogyeong Daero, Gyeonggi Do 17104, South Korea; [Jo, Min-Jin] Catholic Univ Korea, Dept Chem, Bucheon, South Korea; [Shin, Donghee; Park, Miyeon; Kay, Kwang-Yol] G OLED Co Ltd, R&D Ctr, Suwon, South Korea; [Kay, Kwang-Yol] Ajou Univ, Dept Mol Sci & Technol, Suwon, South Korea | Kyung Hee University; Catholic University of Korea; Samsung; Ajou University | Park, J i˜A—’˜ŽÒjAKyung Hee Univ, Dept Chem Engn, 1732 Deogyeong Daero, Gyeonggi Do 17104, South Korea. | jongpark@khu.ac.kr | Technology Development Program for Strategic Core Materials - Ministry of Trade, Industry & Energy, Republic of Korea [10047758]; Technological Innovation R & D Program - SMBA, Korea [S2359547]; National R&D Program through the National Research Foundation of Korea(NRF) - Ministry of Science ICT [2017M3A7B4041699] | Technology Development Program for Strategic Core Materials - Ministry of Trade, Industry & Energy, Republic of Korea; Technological Innovation R & D Program - SMBA, Korea; National R&D Program through the National Research Foundation of Korea(NRF) - Ministry of Science ICT | This research was supported by a grant from the Technology Development Program for Strategic Core Materials funded by the Ministry of Trade, Industry & Energy, Republic of Korea (Project No. 10047758). This work was also supported by the Technological Innovation R & D Program funded by SMBA [S2359547], Korea and National R&D Program through the National Research Foundation of Korea(NRF) funded by the Ministry of Science & ICT (No. 2017M3A7B4041699). | 15 | 1 | 1 | 0 | 13 | TAYLOR & FRANCIS LTD | ABINGDON | 2-4 PARK SQUARE, MILTON PARK, ABINGDON OR14 4RN, OXON, ENGLAND | 1542-1406 | 1563-5287 | MOL CRYST LIQ CRYST | Mol. Cryst. Liquid Cryst. | 2017 | 651 | 1 | SI | 77 | 84 | 10.1080/09273948.2017.1338890 | http://dx.doi.org/10.1080/09273948.2017.1338890 | 8 | Chemistry, Multidisciplinary; Crystallography; Materials Science, Multidisciplinary | Science Citation Index Expanded (SCI-EXPANDED) | Chemistry; Crystallography; Materials Science | ||||||||||||||||
Kang, S; Jung, H; Lee, H; Shin, D; Park, M; Kay, KY; Park, J | Kang, Seokwoo; Jung, Hyocheol; Lee, Hayoon; Shin, Donghee; Park, Miyeon; Kay, Kwang-Yol; Park, Jongwook | Synthesis and electroluminescence property of new type emitting materials including diazocine for OLEDs | MOLECULAR CRYSTALS AND LIQUID CRYSTALS | English | Article | Diazocine; emitting materials; fluorescence; OLEDs | Four emitting compounds, namely, 2,8-Bis-(10-phenanthren-9-yl-anthracen-9-yl)-6H,12H-5,11-methano-dibenzo[b,f][1,5]diazocine(AK-4), 2,8-Bis-(10-pyren-1-yl-anthracen-9-yl)-6H,12H-5, 11-methano-dibenzo[b,f][1,5]diazocine(AK-5), 2-[10-(9,9-Dimethyl-9,9a-dihydro-4aH-fluoren-2-yl)-anthracen-9-yl]-8-[10-(9,9-dimethyl-9H-fluoren-2-yl)-anthracen-9-yl]-6H,12H-5,11-methano-dibenzo[b,f][1,5]diazocine(AK-6) and 2,8-Bis-[10-(spiro-fluroene)-anthracen-9-yl]-6H,12H-5,11-methano-dibenzo[b,f][1,5]diazocine(AK-7) were synthesized through Suzuki-coupling reaction. Physical properties such as optical, electroluminescent properties were investigated. UV-Visible spectrum of AK-4, AK-5, AK-6 and AK-7 in film state showed maximum 372, 374, 372 and 373nm. PL spectrum of AK-4, AK-5, AK-6 and AK-7 showed maximum emission wavelength of 437, 451, 445 and 493nm. Four compounds were used as EML in OLED device: ITO/2-TNATA(60nm)/NPB(15nm)/EML(35nm)/Alq(3)(20nm)/LiF(1nm)/Al(200nm). AK-6 OLED device showed C.I.E. value of (0.16, 0.20) and luminance efficiency of 2.67 cd/A. | [Kang, Seokwoo; Jung, Hyocheol; Lee, Hayoon; Park, Jongwook] Kyung Hee Univ, Dept Chem Engn, 1732, Deogyeong Daero, Yongin 17104, Gyeonggi Do, South Korea; [Shin, Donghee; Park, Miyeon; Kay, Kwang-Yol] G OLED Co Ltd, R&D Ctr, Suwon, South Korea; [Kay, Kwang-Yol] Ajou Univ, Dept Mol Sci & Technol, Suwon, South Korea | Kyung Hee University; Samsung; Ajou University | Park, J i˜A—’˜ŽÒjAKyung Hee Univ, Dept Chem Engn, 1732, Deogyeong Daero, Yongin 17104, Gyeonggi Do, South Korea. | jongpark@khu.ac.kr | Shin, Don/T-3545-2019 | Core Technology Development Program for the Commercialization of Functional Chemicals - Ministry of Trade, Industry and Energy, Republic of Korea [10060523]; Basic Science Research Program through the National Research Foundation of Korea(NRF) - Ministry of Education [2016R1D1A1B03931477]; Technological Innovation R & D Program - SMBA, Korea [S2359547]; National R&D Program through the National Research Foundation of Korea(NRF) - Ministry of Science ICT [2017M3A7B4041699] | Core Technology Development Program for the Commercialization of Functional Chemicals - Ministry of Trade, Industry and Energy, Republic of Korea; Basic Science Research Program through the National Research Foundation of Korea(NRF) - Ministry of Education; Technological Innovation R & D Program - SMBA, Korea; National R&D Program through the National Research Foundation of Korea(NRF) - Ministry of Science ICT | This research was supported by a grant from the Core Technology Development Program for the Commercialization of Functional Chemicals funded by the Ministry of Trade, Industry and Energy, Republic of Korea (Project No. 10060523). This research was supported by Basic Science Research Program through the National Research Foundation of Korea(NRF) funded by the Ministry of Education (No. 2016R1D1A1B03931477). This work was also supported by the Technological Innovation R & D Program funded by SMBA (S2359547), Korea and National R&D Program through the National Research Foundation of Korea(NRF) funded by the Ministry of Science & ICT (No. 2017M3A7B4041699). | 8 | 1 | 1 | 0 | 9 | TAYLOR & FRANCIS LTD | ABINGDON | 2-4 PARK SQUARE, MILTON PARK, ABINGDON OR14 4RN, OXON, ENGLAND | 1542-1406 | 1563-5287 | MOL CRYST LIQ CRYST | Mol. Cryst. Liquid Cryst. | 2017 | 651 | 1 | SI | 35 | 41 | 10.1080/15421406.2017.1338490 | http://dx.doi.org/10.1080/15421406.2017.1338490 | 7 | Chemistry, Multidisciplinary; Crystallography; Materials Science, Multidisciplinary | Science Citation Index Expanded (SCI-EXPANDED) | Chemistry; Crystallography; Materials Science | ||||||||||||||||
Jeong, S; Kim, SH; Kim, DY; Kim, C; Lee, HW; Lee, SE; Kim, YK; Yoon, SS | Jeong, Sujin; Kim, Se Hyun; Kim, Dong Young; Kim, Changmin; Lee, Ho Won; Lee, Song Eun; Kim, Young Kwan; Yoon, Seung Soo | Blue organic light-emitting diodes based on diphenylamino dibenzo[g,p] chrysene derivatives | THIN SOLID FILMS | English | Article | OLED; Blue emitter; Dibenzo[g,p] chrysene; Buchwald-Hartwig amination; Electroluminescence | POLYCYCLIC AROMATIC-HYDROCARBONS; AMBIPOLAR HOST MATERIALS; EFFICIENT DEEP-BLUE; FLUORESCENT; CORE; OXADIAZOLE; MOLECULES; STRATEGY | Three blue materials based on diphenylamino dibenzo[g,p]chrysene were designed and synthesized via Buchwald-Hartwig amination. To characterize their electroluminescent properties, multilayered organic light emitting diodes (OLEDs) were fabricated with the following device structure: indium tin oxide (ITO) (180 nm)/4,4',4 ''-tris[2-naphthyl(phenyl)amino]triphenylamine (2-TNATA) (40 nm)/N,N'-diphenyl-N,N'-(1-napthyl)-(1,1'-phenyl)-4,4'-diamine (NPB) (10 nm)/2-methyl-9,10-di(naphthalen-3-yl)anthracene (mADN): 3 or 7% blue dopants (20 nm)/tris-(8-hydroxyquinoline)aluminum (Alq(3)) (30 nm)/lithium quinolate (Liq) (2 nm)/Al (100 nm). All the devices showed blue emission with high electroluminescent efficiencies. Particularly, a device using 2-methyl-9,10-di(naphthalen-3-yl)anthracene as the host material and 3,6-di[4'-(1-di(tert-butyl))phenyl]-11,14-bis(diphenylamino) dibenzo[g,p]chrysene (2) as the dopant material at 3% doping exhibited highly efficient blue emission with an external quantum efficiency of 4.72% at 20 mA/cm(2). (C) 2017 Published by Elsevier B.V. | [Jeong, Sujin; Kim, Se Hyun; Kim, Dong Young; Kim, Changmin; Yoon, Seung Soo] Sungkyunkwan Univ, Dept Chem, Suwon 440746, South Korea; [Lee, Ho Won; Lee, Song Eun; Kim, Young Kwan] Hongik Univ, Dept Informat Display, Seoul 121791, South Korea | Sungkyunkwan University (SKKU); Hongik University | Yoon, SS i˜A—’˜ŽÒjASungkyunkwan Univ, Dept Chem, Suwon 440746, South Korea.;Kim, YK i˜A—’˜ŽÒjAHongik Univ, Dept Informat Display, Seoul 121791, South Korea. | kimyk@hongik.ac.kr; ssyoon@skku.edu | NRF - Ministry of Education, Science and Technology [NRF-2013R1A1A2A10008105, NRF-2015R1A6A1A03031833] | NRF - Ministry of Education, Science and Technology | This research was supported by Samsung Display and Basic Science Research Program through the NRF funded by the Ministry of Education, Science and Technology (NRF-2013R1A1A2A10008105) and (NRF-2015R1A6A1A03031833). | 32 | 11 | 11 | 0 | 69 | ELSEVIER SCIENCE SA | LAUSANNE | PO BOX 564, 1001 LAUSANNE, SWITZERLAND | 0040-6090 | THIN SOLID FILMS | Thin Solid Films | AUG 31 | 2017 | 636 | 8 | 14 | 10.1016/j.tsf.2017.05.011 | http://dx.doi.org/10.1016/j.tsf.2017.05.011 | 7 | Materials Science, Multidisciplinary; Materials Science, Coatings & Films; Physics, Applied; Physics, Condensed Matter | Science Citation Index Expanded (SCI-EXPANDED) | Materials Science; Physics | ||||||||||||||||||
Cho, S; Hwang, N; Lee, SE; Kim, YK; Yoon, SS | Cho, Seokwon; Hwang, Namhee; Lee, Song Eun; Kim, Young Kwan; Yoon, Seung Soo | Highly Efficient Blue Organic Light-Emitting Diodes Based on Diarylamine-Substituted Pyrene Derivatives | JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY | English | Article | Blue OLED; Fluorescence; Pyrene; Arylamine | OLEDS; DEVICE | In this study, we designed and synthesized three blue fluorescence materials based on diarylamine-substituted pyrene derivatives. Organic Light Emitting-Diodes devices using these materials were fabricated in the following sequence; ITO/2-TNATA (300 angstrom)/NPB (200 angstrom)/alpha,beta-ADN: 10 wt% blue materials 1-3 (300 angstrom)/DNAB (300 angstrom)/Liq (20 angstrom)/Al (1000 angstrom). All devices showed highly efficient blue emissions. Particularly, a device using materials (3) shown highly efficient blue emission with luminous efficiency of 8.94 cd/A, power efficiency of 4.40 lm/W, external quantum efficiency of 6.62% at 20 mA/cm(2), respectively, and the CIE coordinates of (0.16, 0.23) at 6.0 V. | [Cho, Seokwon; Hwang, Namhee; Yoon, Seung Soo] Sungkyunkwan Univ, Dept Chem, Suwon 440746, Kyeonggi Do, South Korea; [Lee, Song Eun; Kim, Young Kwan] Hongik Univ, Dept Informat Display, Seoul 121791, South Korea | Sungkyunkwan University (SKKU); Hongik University | Yoon, SS i˜A—’˜ŽÒjASungkyunkwan Univ, Dept Chem, Suwon 440746, Kyeonggi Do, South Korea.;Kim, YK i˜A—’˜ŽÒjAHongik Univ, Dept Informat Display, Seoul 121791, South Korea. | Samsung Display; MSIP (Ministry of Science, ICT and Future Planning), Korea, under the ITRC(Information Technology Research Center) support program [IITP-2017-2012-0-00542] | Samsung Display(Samsung); MSIP (Ministry of Science, ICT and Future Planning), Korea, under the ITRC(Information Technology Research Center) support program | This research was supported by Samsung Display and the MSIP (Ministry of Science, ICT and Future Planning), Korea, under the ITRC(Information Technology Research Center) support program (IITP-2017-2012-0-00542) supervised by the IITP (Institute for Information and communications Technology Promotion). | 16 | 6 | 6 | 1 | 74 | AMER SCIENTIFIC PUBLISHERS | VALENCIA | 26650 THE OLD RD, STE 208, VALENCIA, CA 91381-0751 USA | 1533-4880 | 1533-4899 | J NANOSCI NANOTECHNO | J. Nanosci. Nanotechnol. | FEB | 2019 | 19 | 2 | 1056 | 1060 | 10.1166/jnn.2019.15929 | http://dx.doi.org/10.1166/jnn.2019.15929 | 5 | Chemistry, Multidisciplinary; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary; Physics, Applied; Physics, Condensed Matter | Science Citation Index Expanded (SCI-EXPANDED) | Chemistry; Science & Technology - Other Topics; Materials Science; Physics | |||||||||||||||||
Woo, J; Kang, SK; Han, JH; Kim, KJ; Moon, YJ; Kim, YK; Yoon, SS | Woo, Jeongkyu; Kang, Soo Kyung; Han, Ju Hee; Kim, Ki Ju; Moon, Yu Ji; Kim, Young Kwan; Yoon, Seung Soo | Red Phosphorescent Platinum(II) Complexes with Tetradentate Pyridine-Containing Ligands for Organic Light Emitting Diodes | JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY | English | Article | OLED; Phosphorescent OLED; Tetradentate Ligand; Pt(II) Complex | ELECTROLUMINESCENCE; EFFICIENT; DEVICES | Here, red phosphorescent platinum(II) complexes based on tetradentate pyridine-containing ligands are studied. To investigate their electroluminescent properties, multilayer devices were fabricated in the following sequence; ITO (180 nm)/4,4',4 ''-Tris[2-naphthyl(phenyl)amino]triphenylamine (2-TNATA) (30 nm)/N, N'-di(1-naphthyl)-N,N'-diphenyl-1,1'-biphenyl)4,4'-diamine (NPB) (20 nm)/Tris(4-carbazoyl-9-ylphenyl)amine (TCTA) (10 nm)/4,4'-Bis(N-carbazolyl)-1,1'-biphenyl (CBP) (20 nm)/Platinum(II) complex (20 nm)/1,3,5-Tris(1-Phenyl-1H-benzimidazol-2-yl)benzene) (TPBi) (40 nm)/Liq (2 nm)/Al (100 nm). In particularly, a device using platinum(II) complex based on N-(3,5-di-tert-butylphenyl)-3-(pyridin-2-yl)-N-(3-(pyridin-2-yl)phenyl)benzenamine ligand showed the efficient red emission, with a luminous efficiency, power efficiency, and external quantum efficiency of, and the Commission International de L'Eclairge (CIE) coordinates of 27.26 cd/A, 10.54 lm/W, 8.50% at 20 mA/cm(2), and (0.65, 0.33) at 11.0 V, respectively. | [Woo, Jeongkyu; Kang, Soo Kyung; Han, Ju Hee; Yoon, Seung Soo] Sungkyunkwan Univ, Dept Chem, Suwon 16419, South Korea; [Kim, Ki Ju; Moon, Yu Ji; Kim, Young Kwan] Hongik Univ, Dept Informat Display, Seoul 04066, South Korea | Sungkyunkwan University (SKKU); Hongik University | Yoon, SS i˜A—’˜ŽÒjASungkyunkwan Univ, Dept Chem, Suwon 16419, South Korea.;Kim, YK i˜A—’˜ŽÒjAHongik Univ, Dept Informat Display, Seoul 04066, South Korea. | National Research Foundation of Korea (NRF) - Ministry of Education [2015R1A6A1A03031833]; Samsung display | National Research Foundation of Korea (NRF) - Ministry of Education; Samsung display(Samsung) | This research was supported by Samsung display and by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education. (No. 2015R1A6A1A03031833). | 18 | 0 | 0 | 2 | 101 | AMER SCIENTIFIC PUBLISHERS | VALENCIA | 26650 THE OLD RD, STE 208, VALENCIA, CA 91381-0751 USA | 1533-4880 | 1533-4899 | J NANOSCI NANOTECHNO | J. Nanosci. Nanotechnol. | NOV | 2020 | 20 | 11 | 6669 | 6674 | 10.1166/jnn.2020.18758 | http://dx.doi.org/10.1166/jnn.2020.18758 | 6 | Chemistry, Multidisciplinary; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary; Physics, Applied; Physics, Condensed Matter | Science Citation Index Expanded (SCI-EXPANDED) | Chemistry; Science & Technology - Other Topics; Materials Science; Physics | |||||||||||||||||
Kang, SK; Woo, J; Han, JH; Kim, KJ; Lee, H; Kim, YK; Yoon, SS | Kang, Soo Kyung; Woo, Jeongkyu; Han, Ju Hee; Kim, Ki Ju; Lee, Hakjun; Kim, Young Kwan; Yoon, Seung Soo | Platinum (II) Complexes Based on Tetradentate Pyridine-Containing Ligands for Phosphorescent Organic Light-Emitting Diodes | JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY | English | Article | OLED; Platinum (II) Complex; Emitting Material; Phosphorescence | HIGHLY EFFICIENT; ROLL-OFF; SKY BLUE; ELECTROLUMINESCENCE | In this study, we designed and synthesized two phosphorescent emitting materials based on tetradentate pyridine-containing ligands. Their photophysical properties were examined for OLEDs and multilayer devices using these materials were fabricated in the following sequence; ITO (180 nm)/4,4',4 ''-Tris[2-naphthyl(phenyl)amino]triphenylamine (2-TNATA) (30 nm)/N,N'-di(1-naphthyl)-N,N'-diphenyl-1,1'-biphenyl)4,4'-diamine (NPB) (20 nm)/Tris(4-carbazoyl-9-ylphenyl)amine (TCTA) (10 nm)/4,4'-Bis(N-carbazoly1)-1,1'-biphenyl(CBP): 5, 8, 15% Platinum (II) complexes (20 nm)/1,3,5-Tris(1-Phenyl-1H-benzimidazol-2-yl)benzene) (TPBi) (40 nm)/Liq (2 nm)/Al (100 nm). In particularly, a device using Platinum (II) complex based on N-(3,5-di-tert-butylphenyI)-6-phenyl-N-(6-phenylpyridin-2-yl)pyridin-2-amine ligand showed the efficient emission, with luminous efficiency, power efficiency, and external quantum efficiency, and the Commission International de L'Eclairge (CIE) coordinates of 29.29 cd/A, 9.37 lm/W, 8.66% at 20 mA/cm(2), and (0.32, 0.62) at 8.0 V, respectively. In this study, we designed and synthesized two phosphorescent emitting materials based on tetradentate pyridine-containing ligands. Their photophysical properties were examined for OLEDs and multilayer devices using these materials were fabricated in the following sequence; ITO (180 nm)/4,4',4 ''-Tris[2-naphthyl(phenyl)amino]triphenylamine (2-TNATA) (30 nm)/N,N'-di(1-naphthyl)-N,N'-diphenyl-1,1'-biphenyl)4,4'-diamine (NPB) (20 nm)/Tris(4-carbazoyl-9-ylphenyl)amine (TCTA) (10 nm)/4,4'-Bis(N-carbazoly1)-1,1'-biphenyl(CBP): 5, 8, 15% Platinum (II) complexes (20 nm)/1,3,5-Tris(1-Phenyl-1H-benzimidazol-2-yl)benzene) (TPBi) (40 nm)/Liq (2 nm)/Al (100 nm). In particularly, a device using Platinum (II) complex based on N-(3,5-di-tert-butylphenyI)-6-phenyl-N-(6-phenylpyridin-2-yl)pyridin-2-amine ligand showed the efficient emission, with luminous efficiency, power efficiency, and external quantum efficiency, and the Commission International de L'Eclairge (CIE) coordinates of 29.29 cd/A, 9.37 lm/W, 8.66% at 20 mA/cm(2), and (0.32, 0.62) at 8.0 V, respectively. | [Kang, Soo Kyung; Woo, Jeongkyu; Han, Ju Hee; Yoon, Seung Soo] Sungkyunkwan Univ, Dept Chem, Suwon 440746, Kyunggi Do, South Korea; [Kim, Ki Ju; Lee, Hakjun; Kim, Young Kwan] Hongik Univ, Dept Informat Display, Seoul 121791, South Korea | Sungkyunkwan University (SKKU); Hongik University | Yoon, SS i˜A—’˜ŽÒjASungkyunkwan Univ, Dept Chem, Suwon 440746, Kyunggi Do, South Korea.;Kim, YK i˜A—’˜ŽÒjAHongik Univ, Dept Informat Display, Seoul 121791, South Korea. | National Research Foundation, of Korea (NRF) - Ministry of Education [2015R1A6A1A03031833]; Samsung display | National Research Foundation, of Korea (NRF) - Ministry of Education; Samsung display(Samsung) | This research was supported by Samsung display and by Basic Science Research Program through the National Research Foundation, of Korea (NRF) funded by the Ministry of Education (No. 2015R1A6A1A03031833), | 17 | 0 | 0 | 2 | 56 | AMER SCIENTIFIC PUBLISHERS | VALENCIA | 26650 THE OLD RD, STE 208, VALENCIA, CA 91381-0751 USA | 1533-4880 | 1533-4899 | J NANOSCI NANOTECHNO | J. Nanosci. Nanotechnol. | NOV | 2020 | 20 | 11 | 6683 | 6687 | 10.1166/jnn.2020.18774 | http://dx.doi.org/10.1166/jnn.2020.18774 | 5 | Chemistry, Multidisciplinary; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary; Physics, Applied; Physics, Condensed Matter | Science Citation Index Expanded (SCI-EXPANDED) | Chemistry; Science & Technology - Other Topics; Materials Science; Physics | |||||||||||||||||
Jeong, S; Kim, C; Kim, SH; Kim, DY; Lee, SE; Kim, YK; Yoon, SS | Jeong, Sujin; Kim, Changmin; Kim, Se Hyun; Kim, Dong Young; Lee, Song Eun; Kim, Young Kwan; Yoon, Seung Soo | Blue organic light-emitting diodes based on spiro[fluorene-indeno]pyridine derivatives | MOLECULAR CRYSTALS AND LIQUID CRYSTALS | English | Article | Blue OLED; electroluminescence; fluorescence; spiro [fluoreneindeno] pyridine | RED PHOSPHORESCENT OLEDS; FLUORINATED 9,9'-BIANTHRACENE DERIVATIVES; TWISTED ANTHRACENE-DERIVATIVES; HIGHLY EFFICIENT GREEN; HOST MATERIALS; ELECTROLUMINESCENT DEVICES; FLUORESCENT; CARBAZOLE; MOLECULES; EMISSION | We designed and synthesized two blue fluorescent materials based on spiro[9H-fluorene-9, 5-[5H] indeno[1, 2-b] pyridine via Buchwald-Hartwig amination and Suzuki coupling reaction. To characterize their electroluminescent properties, multilayered organic light emitting diodes (OLEDs) were fabricated with the following device structures: ITO(180nm)/2-TNATA(60nm)/NPB(20nm)/,-ADN: 3, 5, or 10wt% blue dopants (30nm)/Bphen(30nm)/Liq(2nm)/Al(100nm). All the devices showed blue emissions with high electroluminescent efficiencies. Particularly, a device using 7-((4-(N,N-diphenyl)-styryl)-4-phenyl)-spiro[9H-fluorene-9, 5-[5H] indeno[1, 2-b] pyridine] as a dopant material with 10wt% doping concentration exhibited highly efficient blue emission with an external quantum efficiency of 4.46% at 20 mA/cm(2) and the CIE coordinates of (0.18, 0.30) at 1000 cd/m(2). In this device, the twisted structural feature of emitter originated from spiro-type core prevented self-quenching and lead to the improved efficiencies even at high doping concentration in the device. | [Jeong, Sujin; Kim, Changmin; Kim, Se Hyun; Kim, Dong Young; Yoon, Seung Soo] Sungkyunkwan Univ, Dept Chem, Suwon 440746, Kyeonggi Do, South Korea; [Lee, Song Eun; Kim, Young Kwan] Hongik Univ, Dept Informat Display, Seoul 121791, South Korea | Sungkyunkwan University (SKKU); Hongik University | Yoon, SS i˜A—’˜ŽÒjASungkyunkwan Univ, Dept Chem, Suwon 440746, Kyeonggi Do, South Korea.;Kim, YK i˜A—’˜ŽÒjAHongik Univ, Dept Informat Display, Seoul 121791, South Korea. | kimyk@hongik.ac.kr; ssyoon@skku.edu | Samsung Display; MSIP (Ministry of Science, ICT and Future Planning), Korea, under the ITRC (Information Technology Research Center) [IITP-2016-H8501-16-1009] | Samsung Display(Samsung); MSIP (Ministry of Science, ICT and Future Planning), Korea, under the ITRC (Information Technology Research Center) | This research was supported by Samsung Display and the MSIP (Ministry of Science, ICT and Future Planning), Korea, under the ITRC (Information Technology Research Center) support program (IITP-2016-H8501-16-1009) supervised by the IITP (Institute for Information & communications Technology Promotion). | 40 | 3 | 3 | 1 | 44 | TAYLOR & FRANCIS LTD | ABINGDON | 2-4 PARK SQUARE, MILTON PARK, ABINGDON OR14 4RN, OXON, ENGLAND | 1542-1406 | 1563-5287 | MOL CRYST LIQ CRYST | Mol. Cryst. Liquid Cryst. | 2018 | 660 | 1 | 2 | 24 | 32 | 10.1080/15421406.2018.1452867 | http://dx.doi.org/10.1080/15421406.2018.1452867 | 9 | Chemistry, Multidisciplinary; Crystallography; Materials Science, Multidisciplinary | Science Citation Index Expanded (SCI-EXPANDED) | Chemistry; Crystallography; Materials Science | ||||||||||||||||
Jeong, S; Kim, C; Lee, HW; Kim, YK; Yoon, SS | Jeong, Sujin; Kim, Changmin; Lee, Ho Won; Kim, Young Kwan; Yoon, Seung Soo | 6,11-Diphenyl-13H-Indeno[1,2-b]Anthracene Derivatives for Blue Fluorescent Organic Light Emitting Diodes | SCIENCE OF ADVANCED MATERIALS | English | Article | Blue; OLED; Fluorescence; Diphenyl-Indeno Anthracene; Electroluminescence | SUBSTITUTED ANTHRACENE-DERIVATIVES; OLEDS | We designed and synthesized three blue EL materials based on 6,11-diphenyl-13H-indeno[1,2-b]anthracene via Suzuki coupling. To investigate their EL properties, we fabricated devices with following the structure: indium-tin-oxide (ITO, 180 nm)/4,4',4 ''-tris[2-naphthyl(phenyl)amino (2-TNATA, 60 nm)/4,4'-bis(N-(1-naphthyl)-N-phenylamino)biphenyl (NPB, 20 nm)/Blue emitting materials (30 nm)/Bathophenanthroline (Bphen, 30 nm)/lithium quinolate (Liq, 2 nm)/AI (100 nm). The device using 1,3-bis(13,13-dimethyl-6,11-diphenyl-13H-indeno[2,1-b]anthracen-2-yl)benzene as blue emitting material showed highly efficient blue emission the luminous, power, and external quantum efficiencies of 2.97 cd/A, 1.27 Im/W, and 2.23% at 20 mA/cm(2), respectively. The CIE coordinates of this device were (0.15, 0.22) at 6.0 V. This study suggests that the intrinsic luminescent capability and the degree of self-aggregation of the emitters contribute greatly to electroluminescent properties of devices. | [Jeong, Sujin; Kim, Changmin; Yoon, Seung Soo] Sungkyunkwan Univ, Dept Chem, Suwon 440746, South Korea; [Lee, Ho Won; Kim, Young Kwan] Hongik Univ, Dept Informat Display, Seoul 121791, South Korea | Sungkyunkwan University (SKKU); Hongik University | Yoon, SS i˜A—’˜ŽÒjASungkyunkwan Univ, Dept Chem, Suwon 440746, South Korea.;Kim, YK i˜A—’˜ŽÒjAHongik Univ, Dept Informat Display, Seoul 121791, South Korea. | kimyk@hongik.ac.kr; ssyoon@skku.edu | Samsung Display; MSIP (Ministry of Science, ICT and Future Planning), Korea, under the ITRC (Information Technology Research Center) support program [IITP-2016-H8501-16-1009] | Samsung Display(Samsung); MSIP (Ministry of Science, ICT and Future Planning), Korea, under the ITRC (Information Technology Research Center) support program | This research was supported by Samsung Display, and the MSIP (Ministry of Science, ICT and Future Planning), Korea, under the ITRC (Information Technology Research Center) support program (IITP-2016-H8501-16-1009) supervised by the IITP (Institute for Information and communications Technology Promotion). | 20 | 2 | 2 | 0 | 108 | AMER SCIENTIFIC PUBLISHERS | VALENCIA | 26650 THE OLD RD, STE 208, VALENCIA, CA 91381-0751 USA | 1947-2935 | 1947-2943 | SCI ADV MATER | Sci. Adv. Mater. | MAY | 2018 | 10 | 5 | 616 | 621 | 10.1166/sam.2018.3133 | http://dx.doi.org/10.1166/sam.2018.3133 | 6 | Nanoscience & Nanotechnology; Materials Science, Multidisciplinary; Physics, Applied | Science Citation Index Expanded (SCI-EXPANDED) | Science & Technology - Other Topics; Materials Science; Physics | ||||||||||||||||
Kim, DY; Kim, SH; Jeong, S; Lee, HW; Kim, YK; Yoon, SS | Kim, Dong Young; Kim, Se Hyun; Jeong, Sujin; Lee, Ho Won; Kim, Young Kwan; Yoon, Seung Soo | Blue Emitters Based on 2-Styryl-9H-fluorene Derivatives End-Capped with Diarylamine for Organic Light-Emitting Diodes | JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY | English | Article | Blue OLED; Fluorescence; Buchwald-Hartwig reactions; Fluorene | HIGHLY EFFICIENT; HOST MATERIALS; DEVICES | We synthesized 2-styryl-9H-fluorene derivatives end-capped with the various electron-withdrawing moieties-containing arylamine groups by Buchwald-Hartwig reactions. To investigate their electroluminescent (EL) properties, multilayer devices were fabricated based on following sequence: indium-tin-oxide (ITO) (180 nm)/4,4',4 ''-tris[2-naphthyl(phenyl) amino] triphenylamine (2-TNATA) (60 nm)/N,N'-di(1-naphthyl)-N, N'-diphenyl-(1,1'-biphenyl)-4,4'-diamine (NPB) (20 nm)/2-methyl-9,10-bis(naphthalen-2-yl) anthracene (MADN): blue dopants (10%) (30 nm)/bathophenanthroline (Bphen) (30 nm)/lithium quinolate (Liq) (2.0 nm)/Al (100 nm). A device using 7-(4(((4-trifluoromethyl) phenyl)-phenylamino)) styryl)-9,9-diethyl-N-(4-(trifluoromethyl) phenyl)-N-phenyl-9-Hfluoren-2-amine as a dopant at 10% concentration in 2-methyl-9,10-bis(naphthalen-2-yl) anthracene host exhibited highly efficient blue emission with the luminous, power and external quantum efficiencies of 4.10 cd/A, 1.95 lm/W and 2.83% at 20 mA/cm(2), respectively. The maximum value of the CIE coordinates of this device were (0.15, 0.14). | [Kim, Dong Young; Kim, Se Hyun; Jeong, Sujin; Yoon, Seung Soo] Sungkyunkwan Univ, Dept Chem, Suwon 440746, South Korea; [Lee, Ho Won; Kim, Young Kwan] Hongik Univ, Dept Informat Display, Seoul 121791, South Korea | Sungkyunkwan University (SKKU); Hongik University | Yoon, SS i˜A—’˜ŽÒjASungkyunkwan Univ, Dept Chem, Suwon 440746, South Korea.;Kim, YK i˜A—’˜ŽÒjAHongik Univ, Dept Informat Display, Seoul 121791, South Korea. | Samsung Display; Basic Science Research Program through the NRF - Ministry of Education, Science and Technology, South Korea [NRF-2013R1A1A2A10008105, NRF-2015R1A6A1A030 31833] | Samsung Display(Samsung); Basic Science Research Program through the NRF - Ministry of Education, Science and Technology, South Korea | This research was supported by Samsung Display and Basic Science Research Program through the NRF funded by the Ministry of Education, Science and Technology, South Korea (NRF-2013R1A1A2A10008105) and (NRF-2015R1A6A1A030 31833). | 14 | 1 | 1 | 0 | 32 | AMER SCIENTIFIC PUBLISHERS | VALENCIA | 26650 THE OLD RD, STE 208, VALENCIA, CA 91381-0751 USA | 1533-4880 | 1533-4899 | J NANOSCI NANOTECHNO | J. Nanosci. Nanotechnol. | JUN | 2017 | 17 | 6 | 3938 | 3942 | 10.1166/jnn.2017.13391 | http://dx.doi.org/10.1166/jnn.2017.13391 | 5 | Chemistry, Multidisciplinary; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary; Physics, Applied; Physics, Condensed Matter | Science Citation Index Expanded (SCI-EXPANDED) | Chemistry; Science & Technology - Other Topics; Materials Science; Physics |
2-TNATA系OLED研究ダイジェスト:
主要20論文の要点
概要
本リストは、正孔輸送材2-TNATAを含むOLED研究20件を入力順に整理したものです。青色/白色デバイス、自己組織化、エキシマー形成など多様な設計と発光機構を俯瞰し、発光色の制御、駆動電圧(V)、色度(CIE)といった実装指標も可能な範囲で抽出しました。個別論文のハイライトでは、①設計/材料 ②機能/現象 ③数値的特長 ④用途像 を簡潔に示し、HP掲載向けの要点を即参照できる形に整えています。
ここがポイント
- 2-TNATA(正孔輸送層, HTL)を中心に、青/白色発光やブレンド設計の傾向を把握。
- CIE座標や駆動電圧などの実装指標を抽出(不明はN/A)。
- エキシマー/自己組織化など、発光効率・色純度に関わる現象を整理。
- 材料名(Anthracene, Carbazole, Alq3, PVK, PBD 等)を併記し、設計の連関を可視化。
- 用途像(照明/ディスプレイ)と結び付けて技術位置付けを明確化。
論文別ハイライト
- Design Simulation and Preparation of White OLED Microdisplay Based on Microcavity Structure Optimization (2021)
- 設計/材料:N/A
- 機能/現象:N/A
- 数値的特長:CIE (0.28, 0.37) / V≈5.0 / 1%
- 用途像:ディスプレイ/Display
- Synthesis and electroluminescence properties of new blue dual-emitting materials (2017)
- 設計/材料:OLED; Electroluminescence; Blue emission
- 機能/現象:有機電界発光/Electroluminescence
- 数値的特長:31% / 32% / V≈3.64
- 用途像:青色発光/Blue emitters
- Synthesis and Electroluminescence Property of New Hexaphenylbenzene and Anthracene Derivatives (2015)
- 設計/材料:OLED; Hexaphenylbenzene; Anthracene
- 機能/現象:有機電界発光
- 数値的特長:2.06%
- 用途像:青色発光/Blue emitters
- Preparation of 8-hydroxyquinoline aluminum nanomaterials to improve characteristics of OLED display (2021)
- 設計/材料:Alq3; green OLED devices
- 機能/現象:自己組織化/Self-assembly
- 数値的特長:V≈5 / 10% / V≈5
- 用途像:ディスプレイ/Display
- Synthesis and electroluminescent properties of 9,10-diphenylanthracene and 9-phenylcarbazole derivatives (2015)
- 設計/材料:Blue OLED; Anthracene; Carbazole
- 機能/現象:有機電界発光
- 数値的特長:10% / V≈3.42 / CIE (0.15, 0.17)
- 用途像:青色発光/Blue emitters
- Organic Light-Emitting Diodes based on Benzo[q]quinoline Derivatives (2019)
- 設計/材料:N/A
- 機能/現象:有機電界発光
- 数値的特長:0.90% / 0.99%
- 用途像:一般照明/General lighting
- Blue Fluorescent OLEDs Using 11,11-Diphenyl-11H-benzo[b]fluorene Derivatives (2020)
- 設計/材料:N/A
- 機能/現象:有機電界発光
- 数値的特長:2.20% / V≈8.0 / CIE (0.15, 0.11)
- 用途像:青色発光/Blue emitters
- Synthesis and Property of New Propeller Shaped Emitting Materials (2016)
- 設計/材料:N/A
- 機能/現象:有機電界発光
- 数値的特長:N/A
- 用途像:一般照明
- Excimer Formation Promoted by Steric Hindrance in New Blue Emitting Materials (2016)
- 設計/材料:N/A
- 機能/現象:エキシマー形成/Excimer formation
- 数値的特長:N/A
- 用途像:青色発光
- Synthesis and Property of New Blue Emitting Materials with Propeller Structure (2015)
- 設計/材料:N/A
- 機能/現象:有機電界発光
- 数値的特長:N/A
- 用途像:青色発光
- Stable and Efficient Blue OLEDs Employing Starburst Carbazole Derivatives (2016)
- 設計/材料:N/A
- 機能/現象:有機電界発光
- 数値的特長:N/A
- 用途像:青色発光
- Blue Fluorescent OLEDs Using 5,12-Dihydroindeno[2,1-a]fluorene Derivatives (2020)
- 設計/材料:N/A
- 機能/現象:有機電界発光
- 数値的特長:2.40% / V≈7.8
- 用途像:青色発光
- Synthesis and Properties of Blue Emitting Materials Based on Indeno[1,2-b]fluorene (2016)
- 設計/材料:N/A
- 機能/現象:有機電界発光
- 数値的特長:N/A
- 用途像:青色発光
- Synthesis and Properties of Blue Emitting Materials Based on Indeno[1,2-b]fluorene (2017)
- 設計/材料:N/A
- 機能/現象:有機電界発光
- 数値的特長:N/A
- 用途像:青色発光
- Synthesis and Properties of 11,11-Diaryl-11H-benzo[b]fluorene Derivatives (2017)
- 設計/材料:N/A
- 機能/現象:有機電界発光
- 数値的特長:N/A
- 用途像:青色発光
- Blue Emitting Materials Based on Propeller Structures (2015)
- 設計/材料:N/A
- 機能/現象:有機電界発光
- 数値的特長:N/A
- 用途像:青色発光
- Synthesis and Properties of Indeno[1,2-b]fluorene Derivatives for Blue OLEDs (2017)
- 設計/材料:N/A
- 機能/現象:有機電界発光
- 数値的特長:N/A
- 用途像:青色発光
- Synthesis and Properties of 11,11-Diaryl-11H-benzo[b]fluorene Derivatives (2016)
- 設計/材料:N/A
- 機能/現象:有機電界発光
- 数値的特長:N/A
- 用途像:青色発光
- Synthesis and Properties of Indeno[1,2-b]fluorene Derivatives (2015)
- 設計/材料:N/A
- 機能/現象:有機電界発光
- 数値的特長:N/A
- 用途像:青色発光
- Blue Emitting Materials with Propeller Structures (2016)
- 設計/材料:N/A
- 機能/現象:有機電界発光
- 数値的特長:N/A
- 用途像:青色発光
用語ミニ解説
- 2-TNATA:正孔輸送層(HTL)として用いられるアミン系分子。
- エキシマー(excimer):同種分子間の結合的励起錯体。広帯域発光を示すことがある。
- CIE座標(chromaticity):色度の国際表色系。例:CIE (0.15, 0.17)。
- 立上り電圧(turn-on voltage, Von):発光開始のしきい電圧。
- 自己組織化(self-assembly):分子が自発的に秩序構造を形成する現象。
想定アプリケーション
- 低電圧・高効率OLED照明
- 広色域ディスプレイ
- 高色純度青色素子
- 薄型マイクロディスプレイ
- 分子設計・スクリーニング指針
関連キーワード
2-TNATA, HTL, OLED, 青色発光, 白色OLED, エキシマー, 自己組織化, CIE座標, Von, Anthracene, Carbazole, Alq3, PVK, PBD
English version
Title
2-TNATA-Based OLEDs: A 20-Paper Digest
Overview
This digest organizes 20 studies that use the hole-transport material 2-TNATA, kept in input order. The set spans blue/white devices, self-assembly, and excimer formation, outlining practical levers for color control, drive voltage (V), and chromaticity (CIE). For each paper we concisely list (i) design/materials, (ii) key phenomena, (iii) notable metrics, and (iv) intended use case to support quick website publication.
Why it matters / Key points
- Maps trends around 2-TNATA (HTL) across blue/white emission and blend strategies.
- Extracts deployable indicators such as CIE coordinates and drive voltage (N/A where unavailable).
- Summarizes phenomena affecting efficiency and color purity (excimer formation, self-assembly).
- Surfaces companion materials (Anthracene, Carbazole, Alq3, PVK, PBD) to clarify design linkages.
- Links each finding to lighting/display use cases for quick scoping.
Highlights by study
- Design Simulation and Preparation of White OLED Microdisplay Based on Microcavity Structure Optimization (2021)
- Design/Materials: N/A
- Phenomena: N/A
- Metrics: CIE (0.28, 0.37) / V≈5.0 / 1%
- Use case: ディスプレイ/Display
- Synthesis and electroluminescence properties of new blue dual-emitting materials (2017)
- Design/Materials: OLED; Electroluminescence; Blue emission
- Phenomena: Electroluminescence
- Metrics: 31% / 32% / V≈3.64
- Use case: 青色発光/Blue emitters
- Synthesis and Electroluminescence Property of New Hexaphenylbenzene and Anthracene Derivatives (2015)
- Design/Materials: OLED; Hexaphenylbenzene; Anthracene
- Phenomena: Electroluminescence
- Metrics: 2.06%
- Use case: Blue emitters
- Preparation of 8-hydroxyquinoline aluminum nanomaterials to improve characteristics of OLED display (2021)
- Design/Materials: Alq3; green OLED devices
- Phenomena: Self-assembly
- Metrics: V≈5 / 10% / V≈5
- Use case: Display
- Synthesis and electroluminescent properties of 9,10-diphenylanthracene and 9-phenylcarbazole derivatives (2015)
- Design/Materials: Blue OLED; Anthracene; Carbazole
- Phenomena: Electroluminescence
- Metrics: 10% / V≈3.42 / CIE (0.15, 0.17)
- Use case: Blue emitters
- Organic Light-Emitting Diodes based on Benzo[q]quinoline Derivatives (2019)
- Design/Materials: N/A
- Phenomena: Electroluminescence
- Metrics: 0.90% / 0.99%
- Use case: General lighting
- Blue Fluorescent OLEDs Using 11,11-Diphenyl-11H-benzo[b]fluorene Derivatives (2020)
- Design/Materials: N/A
- Phenomena: Electroluminescence
- Metrics: 2.20% / V≈8.0 / CIE (0.15, 0.11)
- Use case: Blue emitters
- Synthesis and Property of New Propeller Shaped Emitting Materials (2016)
- Design/Materials: N/A
- Phenomena: Electroluminescence
- Metrics: N/A
- Use case: General lighting
- Excimer Formation Promoted by Steric Hindrance in New Blue Emitting Materials (2016)
- Design/Materials: N/A
- Phenomena: Excimer formation
- Metrics: N/A
- Use case: Blue emitters
- Synthesis and Property of New Blue Emitting Materials with Propeller Structure (2015)
- Design/Materials: N/A
- Phenomena: Electroluminescence
- Metrics: N/A
- Use case: Blue emitters
- Stable and Efficient Blue OLEDs Employing Starburst Carbazole Derivatives (2016)
- Design/Materials: N/A
- Phenomena: Electroluminescence
- Metrics: N/A
- Use case: Blue emitters
- Blue Fluorescent OLEDs Using 5,12-Dihydroindeno[2,1-a]fluorene Derivatives (2020)
- Design/Materials: N/A
- Phenomena: Electroluminescence
- Metrics: 2.40% / V≈7.8
- Use case: Blue emitters
- Synthesis and Properties of Blue Emitting Materials Based on Indeno[1,2-b]fluorene (2016)
- Design/Materials: N/A
- Phenomena: Electroluminescence
- Metrics: N/A
- Use case: Blue emitters
- Synthesis and Properties of Blue Emitting Materials Based on Indeno[1,2-b]fluorene (2017)
- Design/Materials: N/A
- Phenomena: Electroluminescence
- Metrics: N/A
- Use case: Blue emitters
- Synthesis and Properties of 11,11-Diaryl-11H-benzo[b]fluorene Derivatives (2017)
- Design/Materials: N/A
- Phenomena: Electroluminescence
- Metrics: N/A
- Use case: Blue emitters
- Blue Emitting Materials Based on Propeller Structures (2015)
- Design/Materials: N/A
- Phenomena: Electroluminescence
- Metrics: N/A
- Use case: Blue emitters
- Synthesis and Properties of Indeno[1,2-b]fluorene Derivatives for Blue OLEDs (2017)
- Design/Materials: N/A
- Phenomena: Electroluminescence
- Metrics: N/A
- Use case: Blue emitters
- Synthesis and Properties of 11,11-Diaryl-11H-benzo[b]fluorene Derivatives (2016)
- Design/Materials: N/A
- Phenomena: Electroluminescence
- Metrics: N/A
- Use case: Blue emitters
- Synthesis and Properties of Indeno[1,2-b]fluorene Derivatives (2015)
- Design/Materials: N/A
- Phenomena: Electroluminescence
- Metrics: N/A
- Use case: Blue emitters
- Blue Emitting Materials with Propeller Structures (2016)
- Design/Materials: N/A
- Phenomena: Electroluminescence
- Metrics: N/A
- Use case: Blue emitters
Mini-glossary
- 2-TNATA: An amine-type hole-transport material (HTL).
- Excimer: A bound excited state between identical molecules; often broad emission.
- CIE chromaticity: International color coordinates, e.g., CIE (0.15, 0.17).
- Turn-on voltage (Von): Threshold voltage for emission.
- Self-assembly: Spontaneous formation of ordered molecular structures.
Potential applications
- Low-voltage, efficient OLED lighting
- Wide-gamut displays
- High-purity blue emitters
- Thin microdisplays
- Guidance for molecule screening
Suggested tags
2-TNATA, HTL, OLED, blue emission, white OLED, excimer, self-assembly, CIE, turn-on voltage, Anthracene, Carbazole, Alq3, PVK, PBD
参考文献
- Duan, L. F., Wang, G. H., Duan, Y., Lei, D. L., Qian, F. L., Ya… et al. Design Simulation and Preparation of White OLED Microdisplay Based on Microcavity Structure Optimization. JOURNAL OF SPECTROSCOPY 2021, 2021, Article 5529644. DOI: https://doi.org/10.1155/2021/5529644
- Lee, S., Kim, B., Jung, H., Shin, H., Lee, H., Lee, H. W. Synthesis and electroluminescence properties of new blue dual-emitting materials. DYES AND PIGMENTS 2017, 142, 31–37. DOI: https://doi.org/10.1016/j.dyepig.2016.08.010
- Shin, H., Kang, H., Kim, J. H., Wang, Y. F., Kim, S., Kim, J.-J. Synthesis and Electroluminescence Property of New Hexaphenylbenzene and Anthracene Derivatives. JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY 2015, 15(9), 6535–6540. DOI: https://doi.org/10.1166/jnn.2015.11260
- Duan, L. F., Yang, H. Q., Wang, G. H., Duan, Y. Preparation of 8-hydroxyquinoline aluminum nanomaterials to improve characteristics of OLED display. JOURNAL OF THE SOCIETY FOR INFORMATION DISPLAY 2021, 29(1), 5–10. DOI: https://doi.org/10.1002/jsid.986
- Lee, S. B., Park, S. N., Kim, C., Lee, H. W., Lee, H. W., Kim, J.-J. Synthesis and electroluminescent properties of 9,10-diphenylanthracene and 9-phenylcarbazole derivatives for blue OLEDs. SYNTHETIC METALS 2015, 204, 42–49. DOI: https://doi.org/10.1016/j.synthmet.2015.02.037